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a b s t r a c tThree model ODS alloys (Fe-0.3Y 2 O 3 , Fe-0.2Ti-0.3Y 2 O 3 and Fe-14Cr-0.2Ti-0.3Y 2 O 3 ) were prepared by ball milling and then hot extrusion to study the effect of Ti and Cr on the size, distribution, crystal structure and composition of the nano-oxide particles. All alloys were characterized by high resolution transmission electron microscopy (HRTEM), atom probe tomography (APT) and synchrotron-X-ray diffraction (S-XRD) to determine the distribution, structure and composition of the oxide nanoparticles samples. The median particle sizes were 9.6 nm, 7.7 nm and 3.7 nm for the Fe-Y 2 O 3 , Fe-Ti-Y 2 O 3 and Fe-Cr-Ti-Y 2 O 3 alloys, respectively, so the presence of Ti resulted in a significant reduction in oxide particle diameter and the addition of Cr gave a further reduction in size. In the Fe-0.3Y 2 O 3 alloy, the particles are found to be bcc Y 2 O 3 , whereas in the other two alloys (Fe-Ti-0.3Y 2 O 3 and Fe-Cr-Ti-Y 2 O 3 ), the oxide particles were found to be structurally consistent with both orthorhombic Y 2 TiO 5 and fcc Y 2 Ti 2 O 7 . Detailed APT studies showed Cr shells around oxide particles of all sizes in the Fe-Cr-Ti-Y 2 O 3 alloy, that a range of cluster compositions are present and that the particle chemistry varies with cluster size. We show that the addition of Cr has a strong effect on both the size and stoichiometry of the particles.

Carbon emission and problems associated with the world have been the major concerns for the past few decades. The world governments have implemented stringent emission norms to reduce the pollution created by hydrocarbon combustion in automobiles. The use of gaseous fuels in IC engines has gained interest among the research community. In the present research work, hydrogen, and oxygen (HHO gas) are produced together in an electrolyzer unit and is fed into the engine intake manifold before the carburetor. The electrolyzer consists of an anode, cathode and five neutral plates made of 316 L SS. Electrolyser production rate was tested with four different molarity conditions of NaOH electrolyte solution ranging from 0.24 to 1 N. It was noted that a maximum of 2 LPM of HHO gas was produced with the supply of 90 A‐h current at 1 N solution concentration. The performance and emission characters of the SI engine were conducted at six different load conditions and four flow rates of HHO gas. HHO gas induction has significantly increased the thermal brake efficiency by 8% and decreased the specific fuel consumption by 20%. With the supply of 2 LPM of HHO gas, CO2, HC, and NOx emissions were reduced by 67%, 59%, and 34%, respectively.

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