An Ag/AgCl electrode used as a corrosion sensor in a reinforced concrete structure is considered as having good application prospect. However, its performance under complex conditions, such as dry-wet cycle condition, is not affirmed. In the current study, the performance of Ag/AgCl as chloride selective electrode in mortar exposed to dry-wet cycle condition was investigated. A simple Ag/AgCl electrode was prepared and fabricated by electrochemical anodization. These Ag/AgCl electrodes were embedded into a mortar specimen with temperature sensors, humidity sensors and anode ladder monitoring system (ALS). After 28 d curing time, the upper surface of mortar specimen was wetted (with 5% NaCl solution) and dried regularly. The obtained results indicate that Ag/AgCl electrode responds to the ingress of chloride ion, sensitively. The chloride ion concentration variation can be reflected by the potential trend. Furthermore, the balance potential of Ag/AgCl electrodes is influenced by dry-wet cycles. Compared with ALS, it demonstrates that Ag/AgCl electrodes are more sensitive to chloride. The research provides the key element for the specific application of Ag/AgCl electrode for corrosion monitoring in the future.
Cement-based materials prepared with activated water induced by a magnetic field or electric field represent a possible solution to environmental issues caused by the worldwide utilization of chemical admixtures. In this contribution, electric- and magnetic-activated water have been produced. The workability and mechanical properties of cement mortar prepared with this activated water have been investigated. The results indicate that the pH and absorbance (Abs) values of the water varied as the electric and magnetic field changed, and their values increased significantly, exhibiting improved activity compared with that of the untreated water. In addition, activated water still retains activity within 30 min of the resting time. The fluidity of the cement paste prepared with electric-activated water was significantly larger than that of the untreated paste. However, the level of improvement differed with the worst performance resulting from cement paste prepared with alternating voltage activated water. In terms of mechanical properties, both compressive strength and flexural strength obtained its maximum values at 280 mT with two processing cycles. The compressive strength increased 26% as the curing time increased from 7 days to 28 days and flexural strength increased by 31%. In addition, through the introduction of magnetic-activated water into cement mortar, the mechanical strength can be maintained without losing its workability when the amount of cement is reduced.
Recently, there is ongoing interest in the use of natural plant fibers as alternatives for conventional reinforcements in cementitious composites. The use of natural plant fibers makes engineering work more sustainable, since they are renewable, biodegradable, energy-efficient, and non-toxic raw materials. In this contribution, a comprehensive experimental program was undertaken to determine the influence of pineapple leaf fiber and ramie fiber on the mechanical properties and mass transport of cement-based composites. The compressive strength, tensile strength, modulus of elasticity, modulus of rupture, fracture energy, flexural toughness, coefficient of capillary water absorption, and chloride diffusion were measured. Natural plant fiber-reinforced cement-based composites (NPFRCCs) containing pineapple leaf fiber and ramie fiber, as compared to the plain control, exhibited a slight reduction in compressive strength and a considerable improvement in tensile strength, modulus of elasticity, modulus of rupture, and flexural toughness; the enhancement was remarkable with a higher fiber content. The coefficient of capillary absorption and chloride diffusion of NPFRCCs were significantly larger than the plain control, and the difference was evident with the increase in fiber content. The present study suggests that the specimen with 2% pineapple leaf fiber content can be used in normal environments due to its superior mechanical properties. However, one should be careful when using the material in marine environments.
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