Potential‐induced degradation (PID) is a solar cell‐related degradation mechanism due to high potential difference in a photovoltaic (PV) module between the solar cells and its grounded frame. This type of degradation is well known for silicon PV; however, for perovskites it has not been thoroughly researched yet. Herein, the PID of perovskite solar cells is investigated for bias voltages of ±500 V, half of the currently used system voltage, and ±1000 V with regular I–V and electroluminescence measurements during the test. The devices show a high PID resistance under applied bias of ±500 V, far exceeding the recommended guidelines for silicon PV. However, for the bias voltage of –1000 V a rapid degradation is observed due to the ingress of sodium ions from the glass substrate as confirmed by the time‐of‐flight secondary ion mass spectrometry measurements of spatial and depth distribution of elements in solar cells. Positively biased devices show no degradation due to high voltage exposure. These results show promising signs that perovskite solar cells are PID proof for current PV system designs.
The
influence of the flooding gas during ToF-SIMS depth profiling
was studied to reduce the matrix effect and improve the quality of
the depth profiles. The profiles were measured on three multilayered
samples prepared by PVD. They were composed of metal, metal oxide,
and alloy layers. Dual-beam depth profiling was performed with 1 keV
Cs
+
and 1 keV O
2
+
sputter beams and
analyzed with a Bi
+
primary beam. The novelty of this work
was the application of H
2
, C
2
H
2
,
CO, and O
2
atmospheres during SIMS depth profiling. Negative
cluster secondary ions, formed from sputtered metals/metal oxides
and the flooding gases, were analyzed. A systematic comparison and
evaluation of the ToF-SIMS depth profiles were performed regarding
the matrix effect, ionization probability, chemical sensitivity, sputtering
rate, and depth resolution. We found that depth profiling in the C
2
H
2
, CO, and O
2
atmospheres has some
advantages over UHV depth profiling, but it still lacks some of the
information needed for an unambiguous determination of multilayered
structures. The ToF-SIMS depth profiles were significantly improved
during H
2
flooding in terms of matrix-effect reduction.
The structures of all the samples were clearly resolved while measuring
the intensity of the M
n
H
m
–
, M
n
O
m
–
, M
n
O
m
H
–
, and M
n
–
cluster secondary ions. A further
decrease in the matrix effect was obtained by normalization of the
measured signals. The use of H
2
is proposed for the depth
profiling of metal/metal oxide multilayers and alloys.
Defluorination of polytetrafluoroethylene (PTFE) surface film is a suitable technique for tailoring its surface properties. The influence of discharge parameters on the surface chemistry was investigated systematically using radio-frequency inductively coupled H2 plasma sustained in the E- and H-modes at various powers, pressures and treatment times. The surface finish was probed by X-ray photoelectron spectroscopy (XPS) and time-of-flight secondary ion mass spectrometry (ToF-SIMS). The measurements of water contact angles (WCA) showed increased wettability of the pristine PTFE; however, they did not reveal remarkable modification in the surface chemistry of the samples treated at various discharge parameters. By contrast, the combination of XPS and ToF-SIMS, however, revealed important differences in the surface chemistry between the E- and H-modes. A well-expressed minimum in the fluorine to carbon ratio F/C as low as 0.2 was observed at the treatment time as short as 1 s when plasma was in the H-mode. More gradual surface chemistry was observed when plasma was in the E-mode, and the minimal achievable F/C ratio was about 0.6. The results were explained by the synergistic effects of hydrogen atoms and vacuum ultraviolet radiation.
A coupled process of ultrasonic spray pyrolysis and lyophilisation was used for the synthesis of dried gold nanoparticles. Two methods were applied for determining their melting temperature: uniaxial microcompression and differential scanning calorimetry (DSC) analysis. Uniaxial microcompression resulted in sintering of the dried gold nanoparticles at room temperature with an activation energy of 26–32.5 J/g, which made it impossible to evaluate their melting point. Using DSC, the melting point of the dried gold nanoparticles was measured to be around 1064.3°C, which is close to pure gold. The reason for the absence of a melting point depression in dried gold nanoparticles was their exothermic sintering between 712 and 908.1°C.
Unambiguous evidence is presented that the chloride ions play a dual role in the formation of a micrometre thick film of polymerized [Cu-Cl-MBI]
n
. This occurs when the copper is exposed to 3 wt.% NaCl solution containing 1 mM of mixture of inhibitors 2-mercaptobenzimidazole, MBI, and octylphosphonic acid, OPA, in the molar ratio MBI:OPA of 9:1. The chloride ions act simultaneously as a promoter of polymerized [Cu–MBI]
n
/[Cu–Cl–MBI]
n
film formation and a reactant that is incorporated in the film, as confirmed by time-of-flight secondary ion mass spectrometry. Also, formation of a Cu2O film under the Cu-inhibitor film was proven by focused ion beam microscopy, with chemical analysis being employed at the cross-section of the thick polymerized film. The Cu(I) oxide underlayer, together with the porous straw-like morphology of the [Cu–Cl–MBI]
n
overlayer, is believed to be responsible for the excellent corrosion protection of copper, even in a chloride environment without the reservoir of MBI+OPA. We also report a new insight into the mechanism of degradation of the Cu–MBI/Cu–Cl–MBI film that results in the formation of (MBI)2 dimers. The inhibitor layer, formed in NaCl solution and containing the synergistic combination of MBI and OPA, showed outstanding resistance to degradation.
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