Addition of high-energy-density materials such as aluminum (Al) microparticles or nanoparticles to liquid propellants potentially improves performance of the fuel. We report on the effects of untreated, prestressed, and superquenched aluminum particles with diameters of 100 nm, 250 nm, 500 nm, 1.6 μm, and 8.8 μm on the combustion of JP-10 droplets acoustically levitated in an oxygen–argon atmosphere. Ignition was initiated by a carbon dioxide laser, and the resulting oxidation processes were traced by Raman, Fourier-transform infrared (FTIR), and ultraviolet–visible (UV–vis) spectroscopies together with high-speed optical and IR thermal-imaging cameras. The UV–vis emission spectra reveal that the key reactive radical intermediates hydroxyl (OH), methylidyne (CH), dicarbon (C2), aluminum monoxide (AlO), and aluminum monohydride (AlH) were formed in addition to atomic aluminum (Al) and the final oxidation products of JP-10, namely, water (H2O) and carbon dioxide (CO2). The Al particles facilitated ignition of the JP-10 droplets and produced higher temperatures in the combustion process of up to typically 2600 K. The effect of the Al particles on the ignition and maximum flame temperatures increased as the diameters reduced. The different stress treatments did not produce observable changes for the ignition or combustion of the droplets, which indicates that the liquid propellant was not significantly affected by manipulating the mechanical properties of the fuel particle additive. The initiation and enhancement of the combustion were a consequence of forming highly reactive atomic oxygen (O) and aluminum monoxide (AlO) radicals in the reaction of aluminum atoms with molecular oxygen in the gas phase. These radicals initiate the degradation of JP-10 via atomic hydrogen abstraction forming the hydroxyl (OH) and aluminum hydroxide (AlOH) radicals in reactions which are mainly exothermic by up to 68 kJ mol–1. In contrast, hydrogen abstractions from JP-10 by molecular oxygen or atomic aluminum are strongly endothermic by up to 236 kJ mol–1, thus making these reactions less competitive. The generation of C10H15 hydrocarbon radicals from the JP-10 initiates successive oxidations and chain reactions with molecular oxygen leading eventually to carbon dioxide and water. These combined experimental results provide insight into how aluminum particles facilitate the oxidation and reaction mechanisms of JP-10 droplets.

No abstract

No abstract

No abstract

No abstract

A high-velocity impact-ignition testing system was used to study the dynamic response of brittle thermite projectiles impacting an inert steel target at velocities of 850 and 1200 m/s. The projectiles included consolidated aluminum and bismuth trioxide that were launched by a propellant driven gun into a catch chamber equipped with high-speed imaging diagnostics. The projectiles passed through a break-screen at the entrance to the chamber and either fragmented upon penetrating the break-screen or remained intact prior to impacting the steel target. In all cases, the projectiles pulverized upon impact, and a reacting debris cloud spreads through the catch chamber. At lower impact velocities, the fragmented and intact projectiles produced similar flame spreading rates of 217–255 m/s. At higher impact velocities, the intact projectile produced the slowest average flame spreading rate of 179 m/s because debris rebounding was limited by the length of the projectile and the resulting debris field was highly consolidated in the radial direction. In contrast, the fragmented projectile rebounded into a well dispersed debris cloud with the highest, 353 m/s, flame spreading rate. A kinetic energy flux threshold was proposed as a means for describing the shift in observed debris dispersion and flame spreading rates. A reactivity model was developed based on particle burn times using a computational fluid dynamics code that incorporated heat transfer and particle combustion in a multiphase environment to understand how the particle size influenced flame spreading. Results from the model show a trade-off between faster reactivity and increased drag inhibiting movement for smaller particle debris.

No abstract

No abstract