Electroluminescence spectra of superbright blue and green LEDs based on epitaxial InxGa1−xN/AlyGa1−yN/GaN heterostructures with thin quantum well active layers [1] were studied at currents J = 0.01-20 mA. Spectral maxima of blue and green LEDs are ωmax = 2.58-2.75 eV and ωmax = 2.38-2.45 eV, dependent on the active layer In content. The low energy tails of the spectra are exponential with the parameter E0 = 42-50 meV almost independent of the temperature. The high energy tails of the spectra are exponential with a temperature dependent parameter E1= 20-40 meV. Both parameters (E0, E1) are current independent at J > 0.5 mA. The spectral band can be described by taking into account quantum size effects, impurities and electron-phonon interactions in active layers. A structure in the spectra was detected which can be described by the influence of light interference in the GaN layer on the sapphire substrate. Light intensity was a linear function of the drive current over the interval J = 1-20 mA, and was slightly temperature dependent. In the blue LEDs, the efficiency fall off at low currents (J < 0.7 mA) had a I ~ J4-5 dependence at room temperature. The green LEDs showed no such dependence. The influence of tunnel effects on the efficiency at low currents is discussed. Tunnel radiation spectra with maxima moving with the voltage were detected at low currents in III-N structures.

Changes of luminescence spectra and electrical properties of light-emitting diodes (LED's) based on InGaN/AlGaN/GaN heterostructures were investigated over a long period of operation. Blue and green LED's with InGaN single quantum wells were studied at currents up to 80 mA for 10 2 -2.10 3 hours. An increase of luminescence intensity at operating currents of 15 mA was detected at the 1st stage of aging (100-800 hours) and a slow fall was detected in the 2nd stage. Greater changes of spectra were observed at low currents (< 0.15 mA). A study of charged acceptor distribution in the space charge region has shown that at the 1st stage their concentration grows, and in the 2nd stage, it falls. The models for the two stages are proposed: 1) activation of Mg due to destruction of residual Mg-H complexes; 2) formation of donor vacancies N. A model of defect formation by hot electrons injected into the quantum well is discussed.

Excellent semipolar GaN material quality can be obtained by growing inverse GaN pyramids on full 2 inch c‐plane sapphire when combining the advantages of defect reduction via FACELO and selective area growth for faceted surfaces. The nearly defect free material is obtained by structuring the mask into a honeycomb pattern. When realizing full GaInN/GaN LED structures on those templates a relatively broad emission is observed during electroluminescence measurements. Furthermore, the dominant wavelength is found to be dependent on the applied current density. The pronounced shift is in good agreement with the wavelength shift along one single facet. Gas phase diffusion during the active area growth is believed to be the main reason for the varying indium content. The homogeneity could be influenced by changing the reactor pressure during the active area growth (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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