Changes of luminescence spectra and electrical properties of light-emitting diodes (LED's) based on InGaN/AlGaN/GaN heterostructures were investigated over a long period of operation. Blue and green LED's with InGaN single quantum wells were studied at currents up to 80 mA for 10 2 -2.10 3 hours. An increase of luminescence intensity at operating currents of 15 mA was detected at the 1st stage of aging (100-800 hours) and a slow fall was detected in the 2nd stage. Greater changes of spectra were observed at low currents (< 0.15 mA). A study of charged acceptor distribution in the space charge region has shown that at the 1st stage their concentration grows, and in the 2nd stage, it falls. The models for the two stages are proposed: 1) activation of Mg due to destruction of residual Mg-H complexes; 2) formation of donor vacancies N. A model of defect formation by hot electrons injected into the quantum well is discussed.
Electroluminescence spectra of light-emitting diodes based on InGaN/AlGaN/GaN heterostructures with single and multiple quantum wells (QWs) are analyzed by models of radiative recombination in 2D-structures with band tails. Equations of the model fit spectra quite good in a wide range of currents. Parameters of the fit are discussed and compared for single and multiple QWs. Tunnel effects play a sufficient role in blue LEDs with single QWs at low currents; they can be neglected in LEDs with multiple QWs. A new spectral band was detected at the high energy side of the spectra of green LEDs with multiple QWs; it is attributed with large scale inhomogenities of In distribution in InGaN QWs.)
Tunnel effects in luminescence spectra and electrical properties of blue InGaN/AlGaN/GaN LEDs were studied. The tunnel radiation in a spectral region of 2.1–2.4 eV predominates at low currents (J<0.2 mA). The role of tunnel effects grows as the maximum of the main blue line in LEDs is shifted to short wavelengths. The position of the tunnel maximum ћωmax is approximatly proportional to the voltage eU. The spectral band is described by the theory of tunnel radiative recombination. Current-voltage characteristics have a tunnel component at low direct and reverse currents. The distribution of charged impurities was received from dynamic capacitance measurements. There are charged layers at heterointerfaces and adjacent compensated layers in the structures. There is a high electric field in the active layer. The energy diagram is analysed.
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