Efficient carboxylation of styrene and carbon dioxide by single-atomic copper electrocatalyst

Quan, Yueli; Yu, Ruohan; Zhu, Jiexin; Guan, Anxiang; Lv, Ximeng; Yang, Chao; Li, Si; Wu, Jinsong; Zheng, Gengfeng

doi:10.1016/j.jcis.2021.05.105

Cited by 29 publications

(28 citation statements)

References 45 publications

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“…S2, ESI †). [26][27][28] The wavelet transform (WT) contour plot of SA-Ni-NC had only one intensity maximum at 5.6 ÅÀ1 , which was assigned to the Ni-N bonds rather than Ni-Ni scattering (8.2 ÅÀ1 ). These results clearly prove the dispersion of Ni-N 4 species in SA-Ni-NC (Fig.…”

Section: Resultsmentioning

confidence: 99%

π-Adsorption promoted electrocatalytic acetylene semihydrogenation on single-atom Ni dispersed N-doped carbon

Chen

et al. 2022

J. Mater. Chem. A

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Section: Resultsmentioning

confidence: 99%

π-Adsorption promoted electrocatalytic acetylene semihydrogenation on single-atom Ni dispersed N-doped carbon

Chen

et al. 2022

J. Mater. Chem. A

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“…The electron-rich singleatomic Cu sites exhibited effective activation of CO2 into CO2 − that attack styrene to produce phenyl succinic acid (Figure 16). Cu/N-C offered high Faradaic efficiency, good selectivity, and a high production rate of 92%, 100%, 216 mg•cm −2 •h −1 , respectively [292] .…”

Section: Electrochemical-based Methodsmentioning

confidence: 99%

“…MOFs advanced electrochemical reduction of CO2 [281][282][283][284][285][286][287][288][289][290][291] and electro-carboxylation [292] .…”

Section: Electrochemical-based Methodsmentioning

confidence: 99%

“…Electrocarboxylation of olefins with CO2 is a promising approach to producing valuable compounds of carboxylates (Figure 16). Nitrogen-coordinated single-atomic Cu sites on carbon framework (Cu/N-C) was synthesized via the carbonization of Cu(acac)2@ZIF-8 [292] . Cu/N-C served as an excellent electrocatalyst for electrocarboxylation of styrene with CO2.…”

Section: Electrochemical-based Methodsmentioning

confidence: 99%

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A Review on Removal of Carbon Dioxide (CO2) using Zeolitic Imidazolate Frameworks: Adsorption and Conversion via Catalysis

Abdelhamid

2022

Preprint

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Carbon dioxide (CO2) is one of the culprit causes of global climatic changes. Furthermore, the efficient separation of CO2 from other gaseous mixtures using ZIFs-based materials is vital for several processes such as flue gas separation, gas sweetening, and natural gas processing. Zeolitic imidazolate frameworks (ZIFs)-based materials are emerging adsorbents and catalysts for CO2 gas removal via adsorption and conversion into valuable chemicals. ZIFs-based adsorbents with high adsorption/conversion efficiencies and tunable properties can be achieved by judicious synthesis and fabrication methods. We reviewed ZIF-based materials for CO2 removal via adsorption and catalysis (e.g., cycloaddition, carboxylation, hydrogenation, N-formylation, electrocatalysis, and photocatalysis). In addition, recent development methods such as membrane synthesis and ways to improve the gas separation performance of ZIF membranes were highlighted. The prospective point of view to promote industrial applications and commercialization of ZIF-based materials was briefly discussed. Once challenges such as low performance and reproducibility for ZIFs-based materials are solved, scalability and cost-effectiveness should not become issues.

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“…Cu/N–C offered high Faradaic efficiency, good selectivity, and a high production rate of 92%, 100%, and 216 mg cm −2 h −1 , respectively. [ 292 ]…”

Section: Conversion Of Co2 Via Catalysismentioning

confidence: 99%

Removal of carbon dioxide using zeolitic imidazolate frameworks: Adsorption and conversion via catalysis

Abdelhamid

2022

Applied Organom Chemis

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Carbon dioxide (CO2) is one of the culprit causes of global climatic changes. Furthermore, the efficient separation of CO2 from other gaseous mixtures using zeolitic imidazolate framework (ZIF)‐based materials is vital for several processes such as flue gas separation, gas sweetening, and natural gas processing. ZIF‐based materials are emerging adsorbents and catalysts for CO2 gas removal via adsorption and conversion into valuable chemicals. ZIF‐based adsorbents with high‐adsorption/conversion efficiencies and tunable properties can be achieved by judicious synthesis and fabrication methods. We reviewed ZIF‐based materials for CO2 removal via adsorption and catalysis (e.g., cycloaddition, carboxylation, hydrogenation, N‐formylation, electrocatalysis, and photocatalysis). In addition, recent development methods such as membrane technologies and ways to improve the gas separation performance of ZIF membranes were highlighted. The prospective point of view to promote industrial applications and commercialization of ZIF‐based materials was briefly discussed. Once challenges such as low performance and reproducibility for ZIF‐based materials are solved, scalability and cost‐effectiveness should not become issues.

show abstract

Efficient carboxylation of styrene and carbon dioxide by single-atomic copper electrocatalyst

Cited by 29 publications

References 45 publications

π-Adsorption promoted electrocatalytic acetylene semihydrogenation on single-atom Ni dispersed N-doped carbon

π-Adsorption promoted electrocatalytic acetylene semihydrogenation on single-atom Ni dispersed N-doped carbon

A Review on Removal of Carbon Dioxide (CO2) using Zeolitic Imidazolate Frameworks: Adsorption and Conversion via Catalysis

Removal of carbon dioxide using zeolitic imidazolate frameworks: Adsorption and conversion via catalysis

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