For groundwater treatment, the technologies involving oxidation on MnOx filter bed are beneficial, common, and effectively used. The presence of MnOx is the mutual feature of filter media, both MnOx-coated mineral materials like quartz sand and gravel, chalcedonite, diatomite, glauconite, zeolite, or anthracite along with consisting of MnOx manganese ores. This review is based on the analysis of research and review papers, commercial data sheets, and standards. The paper aimed to provide new suggestions and useful information for further investigation of MnOx filter media for groundwater treatment. The presented compilations are based on the characteristics of coatings, methods, and conditions of its obtaining and type of filter media. The relationship between the properties of MnOx amendments and the obtained purification effects as well as the commonly used commercial products, their features, and applications have been discussed. The paper concludes by mentioning about improving catalytic/adsorption properties of non-reactive siliceous media opposed to ion-exchange minerals and about possible significance of birnessite type manganese oxide for water treatment. Research needs related to the assessment of the use MnOx filter media to heavy metals removal from groundwater in field operations and to standardize methodology of testing MnOx filter media for water treatment were identified.

On the basis of the registered indications of the water meter, a study on the size and variability of water consumption on the WULS campus in the academic years 2012/16 is presented. The average specific water consumption at a time when classes are implemented amounted to 26.6 dm 3 per student per day for full-time studies student and 19.7 dm 3 per student per day for the student part-time studies. During the holiday season, the rates are lower at 18.4 and 11.8 dm 3 per student per day, respectively. These ratios were determined without taking the water consumption in the dorms into account. The daily peaking factor amounted (N d) to 1.36, while the hourly peaking factor (N h), reached 1.71. Within the week cycle, the highest water consumption was observed in Tuesdays and the lowest-in Sundays. The average Tuesday demands are 40% higher than the Sunday demands. The water consumption peaks during the day occur between 11 a.m. and 1 p.m. as well as 11 p.m. and 1 a.m. The hourly structure of the water distribution in the WULS-SGGW campus is similar to the weekend structure of water distribution in multi-family residential buildings, with the exception of the later occurrence of the evening summit.

The study aimed to determine the nature of the kinetics of the manganese sorption process on Ukrainian tuff and basalt at different temperatures characteristic of the natural water environment. The scope of the research included manganese sorption kinetic test on natural mineral sorbents at temperatures of 10, 17.5 and 25 °C in slightly acidic conditions. Sorption (pseudo-first order, pseudo-second order and Elovich models) and diffusion kinetic models (liquid film diffusion and intraparticle diffusion) were used in the analysis of test results. The manganese sorption process on both tuff and basalt proceeded quickly. The dynamic equilibrium state of manganese sorption settled after 35 and 45 min on tuff and basalt respectively. Although the process took place in a slightly acidic environment and below pHPZC of the sorbents, possible electrostatic repulsion did not inhibit the removal of Mn. The Mn sorption on both materials followed the PSO kinetics model. Based on the diffusion kinetic models, it was determined that Mn sorption process on both materials was influenced by diffusion through the boundary layer and intraparticle diffusion. The differences in removal efficiency and rate of Mn sorption in the temperature range of 10–25 °C were not found.

Bridges in Ukraine are one of the most important components of the infrastructure, requiring attention from government agencies and constant funding. The object of the study was the methodology for quantifying the condition of bridge components. The Artificial Neural Network-based (ANN) tool was developed to quantify the technical condition of bridge components. The literature analysis showed that in most cases the datasets were obtained during the inspection of bridges to solve the problems of assessing the current technical condition. The lack of such a database prompted the creation of a dataset on the basis of the Classification Tables of the Operating Conditions of the Bridge Components (CT). Based on CTs, five datasets were formed to assess the condition of the bridge components: bridge span, bridge deck, pier caps beam, piers and abutments, approaches. The next step of this study was creating, training, validating and testing ANN models. The network with ADAM loss function and softmax activation showed the best results. The optimal values of MAPE and R2 were achieved at the 100th epoch with 64 neurons in the hidden layer and were equal to 0.1% and 0.99998, respectively. The practical application of the ANN models was carried out on the most common type of bridge in Ukraine, namely, a road beam bridge of small length, made of precast concrete. The novelty of this study consists of the development of a tool based on the use of ANN model, and the proposal to modify the methodology for quantifying the condition of bridge components. This will allow minimizing the uncertainties associated with the subjective judgments of experts, as well as increasing the accuracy of the assessment.

Manganese is an undesirable element in tap water but is common in the groundwater. Several methods can be used for manganese removal, including adsorption. Mined rocks are commonly evaluated as adsorbents and it was the objective of this paper-to investigate the Ukrainian volcanic tuff and basaltic rock from the Ivanodolinsky quarry and compare it with Ukrainian zeolite as well as with literature data. The research was based on equilibrated batch tests at a temperature of 10°C and slightly acidic pH. The data were treated using Langmuir and Freundlich models in the linear form. The results indicated the spontaneous and favourable adsorption of manganese. The volcanic tuff was characterized by the highest adsorption capacity, twice higher than basalt and zeolite. The heterogeneity of the active adsorption sites on the tuff was also greater and resulted from the diversity of the mineral composition. Considering the literature data, the properties of tuff are worth further research.

Coagulation is often used for the pre-treatment of industry wastewater, with effectiveness strictly dependent on technological conditions. This study aimed at determining what technological parameters of coagulation of cosmetic industry wastewater provide the highest efficiency of clarification. The dosages of reagents, the order of dosing, as well as the one-and two-stage processes were investigated. The samples of raw wastewater were collected from average daily effluent from a cosmetics manufacturing plant. Liquid coagulant PIX 111 (FeCl 3 ) and NaOH as a pH-adjusting agent were used. Jar-test experiments were carried out to determine the optimum conditions for turbidity and total organic carbon (TOC) removal. The efficiency of clarification was high (90-99%) across a wide range of pH values (6-9) and coagulant doses (0.5-1.25 mL/L). What is important is that the coagulant dose of 0.56 mL/L provided 97.6% clarification efficiency without the addition of the alkali. The minimal stoichiometric excess of alkalinity for effective coagulation was 0.5 mmol/L. In all samples, the removal efficiency for TOC was lower than for turbidity, because some of the organic carbon forms were non-coagulating dissolved compounds. The wastewater from tonic and fluid production was very susceptible to coagulation. The addition of the coagulant before the alkali resulted in better wastewater treatment efficiency than the reverse order. Single-stage process with optimal doses of the reagents allowed to clarify wastewater to a level of 10 NTU. On the other hand, the two-stage process brought the turbidity down to 1 NTU level.

У статті звернено увагу на один з перспективних освітніх методів, запропонованих сучасними інформаційними технологіями,віртуальну реальність, яка моделюється комп'ютером. Реальних досліджень віртуальної реальності в педагогіці здійснюється вкрай мало. Автори наявних праць зводять застосування технологій віртуальної освіти до використання електронних підручників і тестових оболонок, рідше мультимедійних матеріалів, в окремих випадкахкомп'ютерних віртуальних симуляторів і тренажерів. Відтак, мета даної статті узагальнення накопиченого досвіду вивчення можливостей використання ВРтехнологій в освітньому процесі. Наведено переваги і недоліки застосування ВРтехнологій в освіті, формати ВР в освіті, а також кращі проекти застосування ВР в навчальному процесі. Окреслено перспективи подальших досліджень.

(1) The mineral deposits are the base resources of materials used in building and environmental engineering applications, especially available locally. Two wells of volcanic tuff deposits in the Khmelnytsky region of Ukraine were investigated in this regard. (2) Physical-mechanical, chemical, and mineralogical analyses of the core samples were carried out. (3) The tuff samples were characterized by visible colour, low compressive strength (4.34–11.13 MPa), and high water absorption (30%). The dominant minerals of the upper horizon were chlorite, pyroxene, kaolinite, quartz, hematite, and calcite, while those of the lower horizon included analcime, quartz, hematite, and calcite. (4) The studied volcanic tuffs seem to be only partly useful for construction applications, and considering their visible colour, the exterior decoration of engineering objects could be possible. The peculiarity of the minerals of the upper horizon is that their crystals consist of Fe2+. An analysis of existing scientific data made it possible to say that these minerals can be considered as an alternative to expensive metallic iron in reducing the toxicity of chromium, uranium, and halogenated organic compounds. The significant presence of hematite allows the application of tuffs to technologies of water purification from As5+, As3+, Cr6+, Cr3+, U6+, Sb5+, and Se4+ oxyanions.