Following
the global actions to phase out perfluoroctanesulfonic
acid (PFOS) a large number of alternative per- and polyfluoroalkyl
substances, with poorly defined hazard properties, are being used
in increasing quantities. Here, we report on the first detection of
the chlorinated polyfluoroalkyl ether sulfonic acid F-53B in biological
samples and determine the tissue distribution and whole body bioaccumulation
factors (BAFwhole body) in crucian carp (Carassius
carassius). Analysis of fish samples from Xiaoqing River
(XR) and Tangxun Lake (TL) demonstrated a similar level of F-53B contamination
with median concentrations in blood of 41.9 and 20.9 ng/g, respectively.
Tissue/blood ratios showed that distribution of F-53B primarily occurs
to the kidney (TL: 0.48, XR: 0.54), gonad (TL: 0.36, XR: 0.54), liver
(TL: 0.38, XR: 0.53), and heart (TL: 0.47, XR: 0.47). Median Log BAFwhole body values for F-53B (XR: 4.124, TL: 4.322) exceeded
regulatory bioaccumulation criterion and were significantly higher
than those of PFOS in the same data sets (XR: 3.430, TL: 3.279). On
the basis of its apparent omnipresence and strong bioaccumulation
propensity, it is hypothesized that F-53B could explain a significant
fraction of previously unidentified organofluorine in biological samples
from China, and regulatory actions for this compound are encouraged.
Fluoropolymer manufacturing is a major historical source of perfluorooctanoic acid (PFOA) on a global scale, but little is known about the emissions, transport, and fate of emerging per- and polyfluoroalkyl substances (PFASs). Here, we performed a comprehensive spatial trend and interyear comparison of surface water and sediment samples from the Xiaoqing River, which receives water discharge from one of the major fluoropolymer manufacturing facilities in China. A suspect screening identified 42 chemical formulas, including the tetramer acid of hexafluoropropylene oxide (HFPO-TeA) and numerous tentatively detected isomers of C9-C14 per- or polyfluoroalkyl ether carboxylic acids (PFECAs). As revealed by the spatial trends and peak area-based sediment-water distribution coefficients, emerging PFASs with 3-9 perfluorinated carbons were transported unimpededly with the bulk water flow having no measurable degradation. Emerging PFASs with >9 perfluorinated carbons displayed more rapidly decreasing spatial trends than shorter-chain homologues in surface water due to increasing sedimentation rates. The presence of HFPO oligomers, monoether PFECAs, monohydrogen-substituted perfluoroalkyl carboxylic acids (PFCAs) and monochlorine-substituted PFCAs could partly be explained by the active use of polymerization aids or the impurities therein. However, further research is encouraged to better characterize the emissions of low-molecular-weight PFASs from fluoropolymers throughout their life-cycle.
Iron oxyhydroxides (FeOOH) are highly reactive minerals of widespread occurrence in natural and industrial settings. These minerals chiefly occur as nano- to submicron-sized particles and are covered by hydroxyl functional groups coordinated to one (-OH), two (μ-OH), or three (μ(3)-OH) underlying iron atoms. These groups are reaction centers for gases, solutes as well as solvents and thereby play important roles in the fate and transformation of natural and industrial compounds. In this work we provide tools to identify hydroxyl groups on distinct crystallographic planes of two important FeOOH polymorphs, namely lepidocrocite (γ-FeOOH) and goethite (α-FeOOH). Fourier transform infrared spectroscopy was used to monitor O-H stretching vibrations of groups on particles with well-defined and distinct morphologies. Spectral responses to proton loadings and thermal gradients were used to assign bands to hydroxyl groups. These efforts were facilitated by the extraction of pure spectral components obtained by multivariate curve resolution. Molecular dynamics simulations of dominant crystallographic planes of the particles guided band assignment procedures by identifying feasible hydrogen bond networks between surface groups. Our findings provide new possibilities for molecular-scale resolution of important gas-phase processes on the surfaces of these important minerals.
We use cryogenic ion vibrational spectroscopy to characterize the structure and fluxionality of the magic number boron cluster B . The infrared photodissociation (IRPD) spectrum of the D -tagged all- B isotopologue of B is reported in the spectral range from 435 to 1790 cm and unambiguously assigned to a planar boron double wheel structure based on a comparison to simulated IR spectra of low energy isomers from density-functional-theory (DFT) computations. Born-Oppenheimer DFT molecular dynamics simulations show that B exhibits internal quasi-rotation already at 100 K. Vibrational spectra derived from these simulations allow extracting the first spectroscopic evidence from the IRPD spectrum for the exceptional fluxionality of B .
Hydroxyl groups on surfaces of well-defined akagan eite (β-FeOOH) particles were identified by Fourier transform infrared spectroscopy. These efforts, assisted by molecular dynamics simulations, enabled the extraction of spectral signatures for these groups of the dominant ( 100), (001), and (010) crystallographic planes. Band assignments were supported by spectral variations induced by proton and chloride adsorption as well as temperature-programmed desorption. Molecular dynamics simulations were used to determine patterns and free energies of formation of hydrogen bonds. Surface FeÀO distances as well as hydrogen-bond numbers were also used to predict proton affinities. All spectral component concentrations display highly comparable responses to proton loadings with those of other FeOOH minerals previously studied with our coupled experimen-talÀtheoretical approach. These similarities underpin common thermodynamic stabilities for hydroxyls of a given Fe nuclearity on different planes of different minerals.
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