Heteroatom‐Stabilized Chiral Framework of Aluminophosphate Molecular Sieves

Song, Xiaowei; Li, Yang; Gan, Lin; Wang, Zhuopeng; Yu, Jihong; Xu, Ruren

doi:10.1002/anie.200803578

Cited by 91 publications

(67 citation statements)

References 27 publications

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“…into the aluminophosphate framework, a series of novel heteroatom-containing chiral aluminophosphate molecular sieves MAPO-CJ40 (M = Co, Mg, Fe, etc.) have been solvothermally synthesized by using diethylamine as SDA ( Song et al 2009b). The framework of MAPO-CJ40 is intrinsically chiral and exhibits a new zeotype structure assigned as JRY (Framework Type Code).…”

Section: (Ii) Lau-zeotype Transition-metal-substituted Aluminophosphatesmentioning

confidence: 99%

Progress in heteroatom-containing aluminophosphate molecular sieves

2012

Proc. R. Soc. A.

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Over the past 30 years, heteroatom-containing aluminophosphate molecular sieves as a prime class of heterogeneous single-site solid catalysts have been quickly developed since the first discovery of aluminophosphate molecular sieves in 1982, and a large variety of such materials with 48 unique zeotype structures have been prepared. This work mainly presents the progress in the development of heteroatom-containing aluminophosphate molecular sieves with new zeolite structures and variable framework compositions in recent years.

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Section: (Ii) Lau-zeotype Transition-metal-substituted Aluminophosphatesmentioning

confidence: 99%

Progress in heteroatom-containing aluminophosphate molecular sieves

2012

Proc. R. Soc. A.

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“…In the resulting frameworks, two such metals either occupy same crystallographical site or occupy crystallographically different sites. Interestingly [18] and Co 12.8 -Al 19.2 (PO 4 ) 32 (SIZ-7) [19].…”

Section: Introductionmentioning

confidence: 97%

Two new bimetallic phosphates assembled from the 4-ring building units and influence of metal on the phase selectivity

et al. 2011

Inorganica Chimica Acta

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“…During the past 5 years, 11 new zeolite framework structures have been solved by single-crystal X-ray diffraction. These are aluminogermanates (PKU-9 (PUN)) [1], silicogermanates (SU-15 (SOF), SU-32 (STW)) [2], gallogermanates (CJ63 (JST), JU-64 (JSR)) [3,4], aluminophosphates (CJ40 (JRY), CJ62 (JSW), CJ69 (JSN)) [3,[5][6][7], the beryllosilicate LSJ-10 (JOZ) [8], and the high-silica zeolite SSZ-57 (*SFN) with a disordered modulated structure [9].…”

Section: Introductionmentioning

confidence: 99%

Structure Determination of Zeolites by Electron Crystallography

Willhammar¹,

Zou²

2016

Green Chemistry and Sustainable Technology

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Electron crystallography has shown to be an important method for structural characterization of zeolites. Electron crystallography is a method which comprises several important advantages over other characterization methods. With the electron as a probe, single-crystal diffraction data can be obtained from crystals million times smaller than what is possible with X-ray methods today. This is an important advantage especially for zeolites since they are often obtained as very small crystals. Electrons also enable the formation of images of a specimen with the atomic resolution. This is of essential importance when studying materials that are very complex or contain disorder. Over the years electron crystallography has been used for structure determination of zeolites. Through methodological advances during the last few years, it has evolved into an even more powerful method with crucial importance for structure determination. This chapter gives an introduction to electron crystallography and various electron crystallographic methods and their combinations with other methods used for structure determination of zeolite materials. Different routes for structure determination are described through examples from recently reported structure determinations.

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Heteroatom‐Stabilized Chiral Framework of Aluminophosphate Molecular Sieves

Cited by 91 publications

References 27 publications

Progress in heteroatom-containing aluminophosphate molecular sieves

Progress in heteroatom-containing aluminophosphate molecular sieves

Two new bimetallic phosphates assembled from the 4-ring building units and influence of metal on the phase selectivity

Structure Determination of Zeolites by Electron Crystallography

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