Highly efficient transparent OLEDs are demonstrated. A novel WO3 buffer layer protects the organics during the sputter deposition of the top ITO electrode. L–J–V and SIMS analysis yield optimized devices with a 60 nm thick WO3 layer. Very high efficiencies of 38 cdA−1 and 30 lm W−1 at 100 cd m−2 are obtained. At the same time the transmittance throughout the visible part of the spectrum exceeds 75%.
Self-organized porous TiO(2) nanotubes (NTs) were prepared on conductive glass by galvanostatic anodizing of sputtered titanium in an NH(4)F /glycerol electrolyte. DC magnetron sputtering at an elevated substrate temperature (500 degrees C) was used to deposit 650 nm thick titanium films. After anodizing, NTs, 830 nm long, with an average external diameter of 92 nm, were grown; this gave a high conversion rate of oxide from titanium (1.9), with a 220 nm thick layer of titanium, which was not oxidized, located at the base of the tubes. The NTs revealed a mainly amorphous structure, which transformed mostly to anatase upon thermal treatment in air at 450 degrees C. The tubes were sensitized by the N719 complex and the resultant photoelectrodes were incorporated into liquid dye solar cells (DSCs) and further tested under back-side illumination. High values of V(oc) (714 mV) were obtained under 1 sun (AM 1.5), assigned to low dark current magnitude and large recombination resistance and electron lifetime. In addition, typical values of fill factors (of the order of 0.62) were attained, in agreement with the estimated ohmic resistance of the cells in combination with low electron transfer resistance at the platinum/electrolyte interface. The overall moderate power conversion efficiency (of the order of 0.3%) was mainly due to the low short-circuit photocurrents (J(sc) = 0.68 mA cm(-2)), which was confirmed further by the corresponding IPCE values (5.2% at 510 nm). The magnitude of J(sc) was attributed to absorbed light losses due to back-side illumination of the cells, the low dye loading (due to the limited thickness of anodic titania) and the high charge transfer resistance at the TiO(2)/conductive substrate due to the presence of barrier layer(s) underneath the tubes. These preliminary results encourage the DSC community to explore further the galvanostatic anodizing of titanium in order to produce highly efficient porous TiO(2) NTs directly on conductive glass. Current work is focusing on achieving complete anodizing of the metal substrate and full transparency for the photoelectrode in order to increase and optimize the resultant cell efficiencies.
We report on magnetic and magnetoresistance measurements in two categories of superconducting Nb films grown via magnetron sputtering and MgB−2 bulk samples. In the first category, films of Tc = 9.25 K were produced by annealing during deposition. In these films, the magnetic measurements exhibited the so-called "second magnetization peak" ("SMP"), which is accompanied by thermomagnetic instabilities (TMI). The characteristic field H fj , where the first flux jump occurs, has been studied as a function of the sweep rate of the magnetic field. Interestingly, in the regime T < 6.4 K, the respective line H fj (T ) is constant, H fj (T< 6.4 K)= 40 Oe. A comparison to TMI observed in MgB2 bulk samples is also performed. Our experimental findings can't be described accurately by current theories on TMI. In the second category, films of Tc = 8.3 K were produced without annealing during deposition. In such films, we observed a peak effect (PE). In high magnetic fields the PE is accompanied by a sharp drop and a narrow hysteretic behavior (∆T < 20 mK) in the measured magnetoresistance. In contrast to experimental works presented in the past, the comparison of our magnetic measurements with the magnetoresistance data suggests that rather the appearance of surface superconductivity than the melting transition of vortex matter, is the cause of the observed behavior.
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