An experimental study to modify Sterculia foetida L. oil (STO) or the corresponding methyl esters (STO FAME) to branched ester derivatives is reported. The transformations involve conversion of the cyclopropene rings in the fatty acid chains of STO through various catalytic as well as stoichiometric reactions. Full conversion of the cyclopropene rings was obtained using Diels-Alder chemistry involving cyclopentadiene in water at 408C without the need for a catalyst. Olefin metathesis reactions were performed using a Grubbs 2nd generation catalyst and cyclopropene ring conversion was !99 and 54 mol% with 2,3-dimethyl-2-butene and 1-octene, respectively. Oxidation reactions were performed using established epoxidation (Sharpless) and dihydroxylation (Prilezhaev) protocols using aqueous hydrogen peroxide as the oxidant. For both reactions, full conversion of the cyclopropene rings was obtained at RT to yield the corresponding a,b-unsaturated ketone in good selectivities. Rearrangement reactions of the cyclopropene rings to the corresponding conjugated diene were successfully performed using homogeneous and heterogeneous palladium catalysts. Excellent conversions (!99%) were obtained using homogeneous palladium catalyst in a biphasic cyclohexane-water mixture (1:1) at 908C. Relevant cold flow properties of all products were determined and compared to crude STO and STO FAME. Best results were obtained for the metathesis products of STO with 1-octene, with a cloud point (CP) and pour point (PP) of À128C.Practical applications: The S. foetida L. tree produces a tropical oil with high potential to be converted to various oleochemical products. The oil contains cyclopropene rings in the fatty acid chains which are known to be very reactive and as such excellent starting materials for various chemical modification reactions. We here report an experimental study on the modifications of STO into novel branched ester derivatives which are prospective products for a range of applications. Examples are the use as cold-flow improvers for biodiesel or biolubricants (ester derivatives with long, aliphatic branches), as reactive building block material for resin, coatings and/or packaging application (derivatives containing unsaturated (cyclic) structures in the fatty acid chains). Abbreviations: APT, attached proton test; 1, methyl esters of STO; 2, methyl esters of Diels-Alder reaction products; 3a, product of metathesis reaction of STO with 2,3-dimethyl-2-butene; 3b, product of metathesis reaction of STO with 1-octene; 4a, methyl esters of 3a; 4b, methyl esters of 3b; 5, product of epoxidation reaction; 6, product of hydroxylation reaction; 7, product of 1,4-addition reaction of STO with noctylMgBr; 8, methyl esters of 7; 9, methyl esters of rearrangement
This study aims to analyze the improvement of the operational performance of Indonesia’s Soekarno-Hatta Airport train through service quality which is mediated by train passenger loyalty and passenger satisfaction. The main problems in this study are the use of the same railway for long-distance train, airport train, and commuter Line train, the limited use of airport railway with four schedules, the headway which becomes 30 minutes since the number of travels becomes 82 trips, and the tariff being applied now is considered as burdening the passengers. The research method uses a quantitative analysis approach with the technique of Structural Equation Modeling-Lisrel. Data collection is done through observation and questionnaire distribution. The respondents are 306 passengers of trains heading for Soekarno-Hatta Airport. The benefit of this study for the domestic railway company is that by improving service quality, passenger loyalty and satisfaction, it will improve the operational performance of airport trains. The result of this research indicates the significant influence of service quality variable on passenger loyalty through passenger satisfaction, the significant influence of service quality variable on operational performance through passenger satisfaction and passenger loyalty as well as the significant influence of passenger satisfaction variable on operational performance through passenger loyalty.
<p><em>This research is on the manufacturing and logistics industry in Indonesia in improving environmental performance. This study aims to implementation of lean management and green supply chain management to environmental performance. The methodology used in this study is primary data, 150 respondents from logistics professionals. This study uses SEM-PLS. The results showed that lean management had no significant effect on environmental performance. The implications of this study are focused on geography and small samples. Green supply chain management is oriented towards the environment in making supply chain decisions to improve environmental performance. </em></p>
The term patriarchy is used to refer to "male power" specifically the power in which male domination of women occurs which is realized in various ways. Men are considered to have more power than women so that people view women as weak and helpless. However, with the participation of women who echoed the spirit of movement in countering the injustice of patriarchal culture, this social change was taken by the media to be socialized through propagation media that focused visual auditivity, for example in films. The paper thesis was intended to look for signs of resistance (resistance) to patriarchal culture in the components of the filmThis research is a qualitative research with qualitative descriptive method, namely by conducting research on signs of resistance against patriarchal culture on the components of Kartini's film. The analysis unit to be used is the scene. The results of the research data are processed by qualitative analysis which is encoded by the three-level theory of social code proposed by John Fiske so that conclusions can be drawn.Based on the results of the study it can be concluded that some film components show signs of resistance to culture such as wardrobe, movement, sound, music, editing, arrangement, and cinematography. These signs after coding are done using the Three levels of the Social Code showing women's representation of the culture of the Patriarchy.Keywords: Resistance, Women, Patriarchal Culture, Signs, Film Components ABSTRAKIstilah patriarki digunakan untuk menyebut “kekuasan laki-laki” khususnya kekuasan yang didalamnya berlangsung dominasi laki-laki atas perempuan yang direalisasikan melalui berbagai cara. Laki-laki dianggap memiliki kekuatan lebih dibanding perempuan sehingga masyarakat memandang perempuan sebagai seorang yang lemah dan tidak berdaya. Namun seiring dengan banyaknya perempuan yang mendengungkan semangat pergerakan dalam melawan ketidakadilan budaya patriarki, gejala sosial ini ditangkap oleh media untuk disosialisasikan kedalam proyeksi media yang bersifat auditif visual, contohnya pada film. Skripsi karya tulis berjudul “Resistensi Perempuan Jawa Terhadap Patriarki (Analisis Makna Tanda Pada Film Kartini)” ini bertujuan untuk mencari tanda-tanda resistensi (perlawanan) terhadap budaya patriarki didalam komponen-komponen film.Penelitian ini merupakan penelitian kualitatif dengan metode deskriptif kualitatif, yaitu dengan melakukan pencarian tanda-tanda resistensi (perlawanan) terhadap budaya patriarki pada komponen-komponen film Kartini. Unit analisis yang akan digunakan adalah scene. Data hasil penelitian diolah dengan analisis kualitiatif yang dikodekan dengan teori three level of social codes yang dikemukakan oleh John Fiske sehingga bisa ditarik beberapa kesimpulan.Berdasarkan hasil kajian dapat disimpulkan bahwa beberapa komponen- komponen film menunjukan tanda-tanda resistensi (perlawanan) terhadap budaya patriarki seperti wardrobe, pergerakan, sound, musik, editing, setting, dan sinematografi. Tanda-tanda tersebut setelah dilakukan pengkodean menggunakan Three level of Social Codes menunjukan representasi perlawanan perempuan Jawa terhadap budaya Patriarki.Kata Kunci : Resistensi, Perempuan, Budaya Patriarki, Tanda, Komponen Film
Research related to the impact of the COVID-19 pandemic on business strategy, information technology, and supply chain agility on firm performance in the medical device industry in Indonesia. The analysis used is the Structural Equation Model (SEM) with the AMOS program. The study had 171 respondents. The findings in this study are that business strategy, information technology, and supply chain agility have a positive and significant influence on firm performance during the COVID-19 pandemic. The practical implication is that business strategies and information technology save companies and society by involving supply chain agility in securing the supply of medical devices in Indonesia. It is recommended that further research consider not only focusing on medical devices but also larger or different areas to elicit different responses. The practical implications provide direction for adopting business strategies, information technology, supply chain agility in improving firm performance.
<p>Research related to loyal customers in the travel industry. The travel industry adopts strategic e-marketing, technological innovation, trust and value to customers. Customers feel satisfied, thus creating customer loyalty. The methodology for this writing was to distribute questionnaires to 240 travel decision makers (managers / directors / owners). The data were analyzed through the SEM research hypothesis using SPSS / AMOS applied to the relationship and hypothesis testing. The results showed that strategic e-marketing, technological innovation, trust and value on customers had a direct and significant positive effect on satisfaction. Customer satisfaction has a direct and significant positive effect on customer loyalty. The implication of writing helps marketing managers to encourage customer satisfaction by fostering trust and value, creating customer loyalty in the travel sector. This novelty research provides new insights in the development of e-marketing strategies and technological innovation has been recognized as a developing concept that has received intense attention from both literature reviews and practitioners. In addition, further empirical research is still needed to investigate all-digital marketing insights around the world. To enrich the theoretical point of view of the proposed model, further research can carry out a comparative study between industry and developing countries.</p>
This study aims to analyze the influence of information and communication technology (ICT) and business strategies on business performance in small and medium enterprises. This research is quantitative, descriptive survey that uses SEM methodology. Data collection is carried out in small and medium enterprises that have a workforce of 5-19 people for small businesses and 20-99 people for medium-sized businesses. Second, small and medium enterprises have assets of 50 million-500 million rupiah for small businesses and more than 500 million to 5 billion rupiah for medium-sized businesses. The number of samples is 250. The results of the study were processed using LISREL 8.80, in the model and hypothesis testing. The results of this study prove that small and medium enterprises are more open in responding to the rapid development in the field of information and communication technology to build competitive advantages against competitors.
<p>This study aims to determine the effect of company reputation and sustainable innovation strategies on business performance in automotive industry companies in Jakarta. Data obtained by distributing questionnaires to 270 respondents. From 270 data collected, all of them can be analyzed. To analyze data using structural equation modeling (SEM) analysis tools. The results of this study prove that business performance is influenced positively and significantly by the company's reputation and innovation strategy. Business performance is most strongly influenced by the innovation strategy. The limitation of this study was only in Jakarta and four car brands. Further research can be developed with different industries and is expected to add variables that can affect business performance in automotive companies such as customer satisfaction, customer trust and customer relationship management and organizational learning.</p>
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