This paper describes research into the low strain rate mechanical properties of polymer bonded explosives (PBXs) and follows on from that presented by Palmer and co-workers in 1993. PBXs are highly filled composite materials comprised of crystals of a secondary explosive supported in ca. 5-10% (by mass) polymeric binder. In general, the modulus of the binder is 10 5 times lower than that of the crystalline explosive, resulting in the behaviour of the composite being heavily influenced by the properties of the binder despite the low concentration present. The Brazilian test, in which a disc of material is loaded diametrically in compression, has been used to generate tensile failure in the materials studied. Three methods of microscopy have been used to examine the nature of failure in two UK compositions and one US material (PBX 9501). Pre-and post-failure optical and electron microscopy examinations of the materials have been undertaken to gain a greater understanding of the role of the microstructure and this has been aided by the use of an environmental scanning electron microscope to follow real-time failure in the PBXs. Failure in all three compositions has been observed to start around the edges of larger filler particles perpendicular to the direction of tensile strain. Compositions with rubbery binders have been observed forming binder filaments which bridge the crack walls, while clean crystal faces are observed on the larger particles. In a composition with a nitrocellulose-based binder, hair-like features of nitrocellulose have been seen sticking out from the failure surfaces and the rougher crack walls.

The compressive strength of the energetic composition EDC37 has been measured at a temperature of 293 ± 2 K over a range of strain rates from 10−8 to 103 s−1, and at a strain rate of 10−3 s−1 over a range of temperatures from 208 to 333 K. The results show that failure stress is a monotonic function of applied strain rate or temperature, which is dominated by the relaxation properties of the polymeric binder; this is confirmed by dynamic mechanical thermal analysis performed on both EDC37 and its binder. Similarities between the compressive strain rate/temperature data sets can be understood by temperature–time superposition; data collected at a strain rate of 10−3 s−1 over a temperature range 208 to 333 K were mapped onto a plot of strain rate dependent strength at 293 K, using an empirically determined sensitivity of −13.1 ± 0.3 K per decade of strain rate. Sample size was noted to have a modest effect on the stress–strain behaviour; small length to diameter ratios gave results consistent with an increased degree of confinement. Samples taken to large strains exhibited strain localization in the form of shear bands.

A study has been made of the mechanical deformation properties of β-HMX, an important secondary explosive. It is shown that under compressive loading twinning takes place on the (101)-plane. At low loads, this twinning is elastic and usually precedes fracture. Cleavage in β-HMX takes place on the {011}-planes. The fracture surface energy of 0.06 J m -2 has been determined by a micro-indentation technique. This compares with a value of 0.045 J m -2 obtained for the thermodynamic surface energy from contact-angle measurements. The values suggest that there is relatively little energy loss by plastic deformation associated with crack propagation in HMX compared with, for example, the secondary explosives PETN and RDX. Despite this brittleness the twin deformation allows β-HMX to undergo large changes of shape: the significance of this in plastic-bonded explosives is commented on.

This paper describes a study of the strength and failure properties of a range of polymer bonded explosives (PBXS). These are composite systems in which small (typically micrometre up to millimetre-sized) explosive crystals are bonded by a polymer (typically 2–10% (by mass)). In PBXS it is important to optimise the mechanical properties, while maintaining a low sensitiveness (i. e. the material is safe to manufacture, store and handle) and high explosiveness (i. e. reacts powerfully to a prescribed stimulus). The Brazilian test, in which a disc-shaped specimen is loaded diametrically, was chosen for the study. The advantages are that relatively small specimens of typically 10 mm diameter and 4 mm thickness can be used, and that the tensile stresses on the central axis are achieved by applying compressive stresses at the anvil so that complicated gripping arrangements are not required. The technique of double-exposure laser speckle photography was chosen to measure the in-plane displacement field. The technique can measure displacements to sub-micrometre accuracy and provide information over the whole specimen surface. These are distinct advantages over strain gauge methods that involve attaching gauges to the specimen and which only give pointwise information. The double-exposure speckle pattern records were interpreted using an automated Young’s fringes method. The PBXS were of three explosive types and those based on HMX were studied systematically for two crystal sizes and three different binder materials, of two different weight percents. In general, compositions based on micronized crystals were the strongest. Polishing techniques were developed to study the deformation of the individual crystals, the points of nucleation of failure and the fracture paths through the PBXS. The failure modes are discussed in terms of various theoretical models. The mechanical twinning which was shown in earlier work to be an important failure mode in β -HMX also takes place in PBXS based on HMX. The general applicability of the techniques developed in this research for other composite systems is emphasized.

This paper describes the response of explosives to stress and impact and in particular the mechanisms of ‘ hot-spot production. Samples in the form of single crystals, powder layers, pressed pellets, gels, polymer bonded explosives (PBXS) and propellants have been studied. Techniques used include a drop-weight facility with transparent anvils which allows photography at microsecond framing intervals, an instrumented drop-weight machine, a miniaturized Hopkinson bar system for high strain rate property measurement, laser speckle for studying the deformation and fracture of PBXS, an automated system for analysing speckle patterns and heat sensitive film for recording the positions and temperatures of hot spots. Polishing and staining methods have been developed to observe the microstructure of PBXS and failure during quasi-static loading. Ignition, when it occurred, took place at local hot-spot sites. Evidence is discussed for a variety of ignition mechanisms including adiabatic shear of the explosive, adiabatic heating of trapped gases during cavity collapse, viscous flow, friction, fracture and shear of added particles and triboluminescent discharge.

This paper examines the influence of microstructure on the quasi-static failure of PBX 9501, a polymer-bonded explosive (PBX) manufactured for the Los Alamos National Laboratory in America. Optical microscopy has been used to examine qualitatively cracked and pristine material. Consequent on the manufacturing process, the explosive crystals display angular features and natural facets. In addition, considerable growth twinning, internal defects and voidage has been observed. These defects are found significantly to alter the failure path. In common with other PBXs, failure paths tend to run around the long straight edges of the explosive filler and avoid regions of fine filler and binder. Explosive crystals were found to fracture due either to cracks propagating from another region or internal defects. These observations are confirmed by the use of high-resolution moiré interferometry. This sensitive optical technique allows the deformation of the sample to be measured up to and including the point of failure. By taking white-light micrographs that are in exact registration with the measured displacement maps, the influence of the underlying microstructure can be seen.

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