An hourly dataset of automatic weather stations over Beijing Municipality in China is developed and is employed to analyze the spatial and temporal characteristics of urban heat island intensity (UHII) over the built-up areas. A total of 56 stations that are located in the built-up areas [inside the 6th Ring Road (RR)] are considered to be urban sites, and 8 stations in the suburban belts surrounding the built-up areas are taken as reference sites. The reference stations are selected by using a remote sensing method. The urban sites are further divided into three areas on the basis of the city RRs. It is found that the largest UHII generally takes place inside the 4th RR and that the smallest ones occur in the outer belts of the built-up areas, between the 5th RR and the 6th RR, with the areas near the northern and southern 6th RR experiencing the weakest UHI phenomena. On a seasonal basis, the strongest UHII generally occurs in winter and weak UHII is dominantly observed in summer and spring. The UHII diurnal variations for each of the urban areas are characterized by a steadily strong UHII stage from 2100 local solar time (LST) to 0600 LST and a steadily weak UHII stage from 1100 to 1600 LST, with the periods 0600-1100 LST and 1600-2100 LST experiencing a swift decline and rise, respectively. UHII diurnal variation is seen throughout the year, but the steadily strong UHII stage at night is longer (shorter) and the steadily weak UHII stage during the day is shorter (longer) during winter and autumn (summer and spring).

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Correlations of the urban heat island intensity (UHII) and key surface variables with the short-duration intense rainfall (SDIR) events are examined for the Beijing urban areas by applying hourly data of a high-density automatic weather station (AWS) network. Higher frequencies (amounts) of the SDIR events are found in or near the central urban area, and most of the SDIR events begin to appear in late evening and nighttime, but tend to end in late night and early morning. Correlations of the UHII with the SDIR frequency (amount) are all highly significant for more than 3 h ahead of the beginning of the SDIR events. Although the UHII at immediate hours (<3 h) before the SDIR occurrence is more indicative of SDIR events, their occurrence more depends on the magnitude of the UHII at earlier hours. The UHII before the beginning of the SDIR events also shows high-value centers in the central urban area, which is generally consistent with the distribution of the SDIR events. The spatial and temporal patterns of regional SDIR events exhibit similar characteristics to the site-based SDIR events and also show a good relationship with the UHII in the urban areas. In addition to the UHII over the urban areas, surface air temperature, surface air pressure, relative humidity, and near-surface wind directions at the Beijing station experience large changes before and after the beginning time of regional SDIR events, and have the potential to indicate the occurrence of SDIR events in the studied area.

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Concentrations of 15 polycyclic aromatic hydrocarbons (PAHs) were measured in surface soils collected from Dalian, China, for examination of distributions and composition profiles and their potential toxicity. The sum of 15 PAHs (SigmaPAHs) ranged from 190 to 8595 ng g(-1) dry weight, and showed an apparent urban-suburban-rural gradient in both SigmaPAHs and composition profiles. Using hierarchical cluster analysis (HCA), the sampling sites were grouped into four clusters corresponding to traffic area, park/residential area, suburban and rural areas. The ratios of naphthalene (Nap) and fluorene (Fl) versus fluoranthene (Flu), pyrene (Pyr) and indeno(1,2,3-cd)pyrene (InP) in the four clusters provided evidence of local distillation. The diagnostic ratios indicated the prevalent PAH sources were petroleum combustion and coal combustion in Dalian, and a cross plot of diagnostic ratios distinguished the urban samples from suburban and rural ones. Toxic potency assessment of soil PAHs presented a good relationship with benzo(a)pyrene (BaP) levels, toxic equivalent concentrations based on BaP (TEQ(BaP)) and dioxin-like toxic equivalent concentrations (TEQ(TCDD)). The study highlights that BaP is a good indicator for assessing the potential toxicity of PAHs, and presents a promising toxicity assessment method for soil PAHs.

ABSTRACT:On basis of quality-control of hourly rainfall dataset of Automatic Weather Stations (AWSs) for the last 4 years (2007)(2008)(2009)(2010), the spatial and diurnal characteristics of summer rainfall in Beijing Municipality (BJM) is analyzed. Results show that the short-duration heavy rainfall events dominate summer rainfall in the study area. Rainfall events with 1-3 h duration make a large contribution to both frequency and amount of summer rainfall, and the total rainfall amount in summer fall almost in the events with duration less than 6 h. Two peaks in diurnal variation of rainfall event frequency are evident, with one in early morning and another in later evening, but only one peak in later evening occurs for diurnal variation of rainfall amount. The exact timing and magnitudes of the peaks vary from one station to another probably due to the influence of the complicated terrains and geographical conditions. Except for the southeast area of the BJM, however, the highest frequency of rainfall events always occurs in evening between 1900 and 2300 (Local Standard Time, or LST), almost consistent to the occurrence time of the maximum rainfall amount. The peak of rainfall event frequency over the southeast area is generally in early morning (0300-0500 LST) which might have been related to the combined influences from land-sea breeze and urbanization.

Hourly datasets obtained by automatic weather stations in Beijing, China, are developed and employed to analyze the spatial and temporal characteristics of relative humidity (RH) and urban dryness island intensity (UDII) over built-up areas. A total of 36 stations inside the sixth ring road are considered as urban sites, while six stations in suburban belts surrounding the built-up areas are taken as reference sites. Results show that the RH is obviously smaller in urban areas than in suburban areas, indicating the effect of urbanization on near-surface atmospheric moisture and RH. A further analysis of relations between RH and temperature on varied time scales shows that the variations in RH in the urban areas are not due solely to changes in temperature. The annual and seasonal mean UDII are high in central urban areas, with the strongest UDII values occurring in autumn and the weakest values occurring in spring. The diurnal UDII variations are characterized by a steadily strong UDII stage from 2000 to 0800 LT and a minimum at 1500 or 1600 LT. The rapid shifts of UDII from high (low) to low (high) occur during the periods 0800–1600 LT (1600–2000 LT). The occurrence time of the peaks varies among different seasons: the peaks appear at 0700, 2100, 2000, and 0800 LT for spring, summer, autumn, and winter, respectively. Further analysis shows that large UDII values appear in the evenings and early nights in late summer and early to midautumn and that low UDII values mainly occur in the afternoon hours of spring, winter, and late autumn.