CsPb(MoO) crystals were prepared by crystallization from their own melt, and the crystal structure has been studied in detail. At 296 K, the molybdate crystallizes in the low-temperature α-form and has a monoclinic palmierite-related superstructure (space group C2/m, a = 2.13755(13) nm, b = 1.23123(8) nm, c = 1.68024(10) nm, β = 115.037(2)°, Z = 16) possessing the largest unit cell volume, 4.0066(4) nm, among lead-containing palmierites. The compound undergoes a distortive phase transition at 635 K and incongruently melts at 943 K. The electronic structure of α-CsPb(MoO) was explored by using X-ray emission spectroscopy (XES) and X-ray photoelectron spectroscopy methods. For α-CsPb(MoO), the photoelectron core-level and valence-band spectra and the XES band representing the energy distribution of Mo 4d and O 2p states were recorded. Our results allow one to conclude that the Mo 4d and O 2p states contribute mainly to the central part and at the top of the valence band, respectively, with also significant contributions throughout the whole valence-band region of the molybdate under consideration.
Thin films of tin doped zinc oxide (ZnO: Sn) with thickness 300 ± 30 nm prepared by spray pyrolysis method at substrate temperatures of 400°C. The structure, surface morphological and optical properties were studied, for Two weight ratios of doping (2 and 4) wt %. The results of X-Ray measurements showed that all deposit samples have a polycrystalline pattern with hexagonal wurtzite type structure. The films crystallites were oriented along (002) plane. The morphology measurements obtained by scanning electron microscope (SEM) showed that there is a change in the surface texture by the increasing of tin weight ratios with the rate of porosity of the surface when treating with 4wt %. The measurement of Atomic force microscopy (AFM) revealed nano particles sized and the roughness of the surface decrease to increase deflection, while optical measurements showed a decrease The energy gap of the models that are expected in the undoped samples.
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