We prepare CuCrO2 thin films with magnesium and nitrogen dopants. The solid state reaction method is employed to produce CuCrO2 targets with three different concentrations of Mg (0%, 2.5%, and 5%). The targets are used in an RF sputtering system to prepare thin films in the presence of N2 as the reactive gas. In this manner, Mg and N atoms, respectively, replace Cr and O sites in the CuCrO2 structure and enhance the electrical and optical properties of the host material. This cationic-anionic substitution yields a superior hole transport and results in an increased conductivity of ∼278 S cm−1 which is considered as a record for p-type conductivity in transparent conducting oxides. Moreover, the co-doped CuCrO2 demonstrates a bandgap of 3.52 eV and a transmittance of about 69% in the visible region.

A novel method of oxide semiconductor nanoparticle synthesis is proposed based on high-voltage, high-current electrical switching discharge (HVHC-ESD). Through a subsecond discharge in the HVHC-ESD method, we successfully synthesized zinc oxide (ZnO) nanorods. Crystallography and optical and electrical analyses approve the high crystal-quality and outstanding optoelectronic characteristics of our synthesized ZnO. The HVHC-ESD method enables the synthesis of ZnO nanorods with ultraviolet (UV) and visible emissions. To demonstrate the effectiveness of our prepared materials, we also fabricated two UV photodetectors based on the ZnO nanorods synthesized using the subsecond HVHC-ESD method. The UV-photodetector test under dark and UV light irradiation also had a promising result with a linear ohmic current−voltage output. In addition to the HVHC-ESD method's excellent tunability for ZnO properties, this method enables the rapid synthesis of ZnO nanorods in open air and water. The results demonstrate the preparation, highlight the synthesis of fine hexagonal-shaped nanorods under a second with controlled oxygen vacancies, and point defects for a wide range of applications in less than a second.

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It is known that the entanglement entropy of a scalar field, found by tracing over its degrees of freedom inside a sphere of radius R, is proportional to the area of the sphere (and not its volume). This suggests that the origin of black hole entropy, also proportional to its horizon area, may lie in the entanglement between the degrees of freedom inside and outside the horizon. We examine this proposal carefully by including excited states, to check probable deviations from the area law.

In this paper, we explore the final stages of the black hole evaporation for Hayward solutions. Our results show that the behavior of Hawking's radiation changes considerably at the small radii regime such that the black hole does not evaporate completely and a stable remnant is left. We show that stability conditions hold for the Hayward solutions found in the Einstein gravity coupled with nonlinear electrodynamics. We analyse the effect that an inspired model of the noncommutativity of spacetime can have on the thermodynamics of Hayward spacetimes. This has been done by applying the noncommutative effects to the non-rotating and rotating Hayward black holes. In this setup, all point structures get replaced by smeared distributions owing to this inspired approach. The noncommutative effects result in a colder black hole in the small radii regime as Hayward's free parameter g increases. As well as the effects of noncommutativity and the rotation factor, the configuration of the remnant can be substantially affected by the parameter g. However, in the rotating solution it is not so sensitive to g with respect to the non-rotating case. As a consequence, Hayward's parameter, the noncommutativity and the rotation may raise the minimum value of energy for the possible formation of black holes in TeV-scale collisions. This observation can be used as a potential explanation for the absence of black holes in the current energy scales produced at particle colliders. However, it is also found that if extra dimensions do exist, then the possibility of the black hole production at energy scales accessible at the LHC for large numbers of extra dimensions will be larger.

We propose and fabricate a heterojunction between Al-doped ZnO and (Mg, N)-doped CuCrO2 thin films using the sputtering deposition method. These materials possess wide bandgap that makes them transparent in the visible light but excellent UV-absorbers. On the other hand, the high conductivity of these materials, respectively as n-type and p-type transparent conducting oxides, facilitates the charge transport. We show that the p–n junction fabricated from these materials has the potential to act as a high-performance UV photovoltaic photodetector. The proposed structure, demonstrates fast responses in order of sub seconds, photosensitivity of ~ 41,000, responsivity of 1.645 mA/W, and a detectivity of 3.52 × 1012 Jones that are significantly improved in comparison with the Al-doped ZnO photoconductor. This excellent improvement is attributed to the capability of the photovoltaic configuration that creates a built-in voltage and facilitates the charge separation and collection rather than recombination in the photoconductor configuration.

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