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Hydrogen has been introduced as a potential replacement for energy resource due to the depletion of fossil fuel and raising awareness about global climate change and health problems caused by the combustion of fossil fuel. One of the attractive options to produce hydrogen is through microbial fermentation which can be classified into biophotolysis, dark fermentation, photofermentation, and microbial electrolysis cell. Among these, dark fermentation and photofermentation technologies were processes that were being studied widely. One of the reasons is that organic waste could be reused as a substrate during biohydrogen production. Although the current biohydrogen yields are low, it is expected that with improvements technology and genetic engineering, the amount of generated biohydrogen could be enhanced tremendously, and provide a sustainable way of reutilizing waste as a substrate. Thus, this paper reviews the principles of photofermentation and dark fermentation by reusing various wastes as substrates. The resulting performances, limitations, as well as future prospects of hydrogen usage and hydrogen economy are also discussed. © 2013 Society of Chemical Industry and John Wiley & Sons, Ltd

Currently, the transformation of lignocellulosic biomass into value-added products such as reducing sugars is garnering attention worldwide. However, efficient hydrolysis is usually hindered by the recalcitrant structure of the biomass. Many pretreatment technologies have been developed to overcome the recalcitrance of lignocellulose such that the components can be reutilized more effectively to enhance sugar recovery. Among all of the utilized pretreatment methods, inorganic salt pretreatment represents a more novel method and offers comparable sugar recovery with the potential for reducing costs. The use of inorganic salt also shows improved performance when it is integrated with other pretreatment technologies. Hence, this paper is aimed to provide a detailed overview of the current situation for lignocellulosic biomass and its physicochemical characteristics. Furthermore, this review discusses some recent studies using inorganic salt for pretreating biomass and the mechanisms involved during the process. Finally, some prospects and challenges using inorganic salt are highlighted.

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