The performance of hydrophobic surfaces under hydraulic pressures is critical to a wide range of practical applications such as drag reduction of seaboard vessels and design of microfluidic devices. This research focuses on the evaluation of drag reduction and velocity slip of hydrophobic surfaces and coatings under external hydrostatic pressures using an acoustic wave device (i.e., quartz crystal microbalance, QCM). The correlation between the resonant frequency shift of a QCM device and drag reduction of hydrophobic surface coated on the QCM was theoretically developed and the model was validated by comparing the measurement results of the drag reduction of an epoxy-based superhydrophobic coating with those measured by a rheometer. The QCM device was further employed to study the wetting state transition and drag reduction of water on a micropillar array based superhydrophobic surface under elevated hydrostatic pressures. It was found that the transition from Cassie to Wenzel states occurred at a critical hydrostatic pressure which was indicated by a sudden frequency drop of the QCM device. In addition, the effective heights of the meniscus at the liquid/air interface increased with the external pressure before the transition took place. The drag reduction induced by the micropillar surface decreased with the increasing hydrostatic pressures. It was demonstrated that the developed QCM based technology provides a low cost, simple, and reliable tool for evaluating hydrophobic performance of various surfaces under external hydrostatic pressures.
This work reports a novel Quartz Crystal Microbalance (QCM) based method to analyze the droplet-micropillar surface interaction quantitatively during dropwise condensation. A combined nanoimprinting lithography and chemical surface treatment approach was utilized to directly fabricate the micropillar based superhydrophobic surface on the QCM substrate. The normalized frequency shift of the QCM device and the microscopic observation of the corresponding nucleation, drop growth, and drop coalescence processes clearly demonstrate the different characteristics of these condensation states. In addition, a synchrosqueezed wavelet spectrum based multi-resolution technique was utilized to analyze the resonant signal from the QCM sensor in both time and frequency domains simultaneously. An integrated discrete system modeling along with a hybrid signal and image processing approach was adopted to identify the response of the micropillars under different stages of dropwise condensation (DWC). The outcome of this signal processing research leads to a fundamental understanding of DWC spanning multiple time and length scales. The proposed study will also contribute to an in-depth understanding of different hydrophobic surfaces and DWC through this advanced signal processing and surface treatment. The developed QCM system provides a valuable tool for the dynamic characterization of different condensation processes.
A durable superhydrophobic coating formulation with epoxy binder thermoset was used to coat on surfaces, which provide high quality for corrosion protection, reduced biofouling and improved hydrodynamic behavior. The single and double layers coating of these nanostructured epoxy were fabricated and coated on a novel quartz crystal microbalance (QCM) technique to investigate their hydrophobic properties. Different static and dynamic wettability were obtained and characterized by evaluating the electrical impedance of QCM coated with nanostructured epoxy in air and DI water. It was found that QCM is able to quantitatively characterize the hydrophobicity of these nanostructured polymer surfaces. For double layer coating, the frequency shift in DI water was smaller in comparison to the single layer one. The reduction in mechanical impedance of QCM clearly demonstrates the effect of enhanced hydrophobicity for both single and double layers. The experimental results show that the hydrophobic surface resulted in smaller mechanical impedance loading, while the hydrophilic surface exerted much larger mechanical impedance. The outcome of this research will build a solid foundation for the further improvement of vehicles coated with superhydrophobic surfaces operating in water and increased equipment life.
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