We have introduced a facile strategy to fabricate sandwich-stacked SnO2/Cu hybrid nanosheets as multichannel anodes for lithium-ion batteries applying rolled-up nanotechnology with the use of carbon black as intersheet spacer. By employing a direct self-rolling and compressing approach, a much higher effective volume efficiency is achieved as compared to rolled-up hollow tubes. Benefiting from the nanogaps formed between each neighboring sheet, electron transport and ion diffusion are facilitated and SnO2/Cu nanosheet overlapping is prevented. As a result, the sandwich-stacked SnO2/Cu hybrid nanosheets exhibit a high reversible capacity of 764 mAh g(-1) at 100 mA g(-1) and a stable cycling performance of ~75% capacity retention at 200 mA g(-1) after 150 cycles, as well as a superior rate capability of ~470 mAh g(-1) at 1 A g(-1). This synthesis approach presents a promising route to design multichannel anodes for high performance Li-ion batteries.
Ti and Ti-TiB composite materials were produced by selective laser melting (SLM). Ti showed an α΄ microstructure, whereas the Ti-TiB composite revealed a distribution of needle-like TiB particles across an α-Ti matrix. Hardness (H) and reduced elastic modulus (Er) were investigated by nanoindentation using loads of 2, 5 and 10 mN. The results showed higher H and Er values for the Ti-TiB than Ti due to the hardening and stiffening effects of the TiB reinforcements. On increasing the nanoindentation load, H and Er were decreased. Comparison of the nanoindentation results with those derived from conventional hardness and compression tests indicated that 5 mN is the most suitable nanoindentation load to assess the elastic modulus and hardness properties. The wear resistance of the samples was related to their corresponding H/Er and H3/Er2 ratios obtained by nanoindentation. These investigations showed that there is a high degree of consistency between the characterization using nanoindentation and the wear evaluation from conventional wear tests
Samples of low modulus beta-type Ti40Nb and cp2-Ti were chemically treated with 98% H2 SO4 + 30% H2 O2 (vol. ratio 1:1) solution. Surface analytical studies conducted with HR-SEM, AFM, and XPS identified a characteristic nanoroughness of the alloy surface related with a network of nanopits of ∼25 nm diameter. This is very similar to that obtained for cp2-Ti. The treatment enhances the oxide layer growth compared to mechanically ground states and causes a strong enrichment of Nb2 O5 relative to TiO2 on the alloy surface. The in vitro analyses clearly indicated that the chemical treatment accelerates the adhesion and spreading of human mesenchymal stromal cells (hMSC), increases the metabolic activity, and the enzyme activity of tissue non-specific alkaline phosphatase (TNAP). Surface structures which were generated mimic the cytoplasmic projections of the cells on the nanoscale. Those effects are more pronounced for the Ti40Nb alloy than for cp2-Ti. The relation between alloy surface topography and chemistry and cell functions is discussed.
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