In this study, carbon nanodots (C-dots)/WO photocatalysts were prepared via a two-step hydrothermal method. The morphologies and optical properties of the as-prepared materials were investigated. Compared with the prepared WO and C-dots, the C-dots/WO possessed stronger photocatalytic capability and excellent recyclability for photocatalytic elimination of Rhodamine B. For example, the achieved first order reaction rate constant of 0.01942 min for C-dots/WO was ∼7.7 times higher than that of the prepared WO. The enhanced photocatalytic activity of C-dots/WO was attributed to the enhanced light harvesting ability and efficient spatial separation of photo-excited electron-hole pairs resulting from the synergistic effect of WO and C-dots. The high photocatalytic activity of C-dots/WO remained unchanged even after 3 cycles of use. Meanwhile, a possible mechanism of C-dots/WO for the enhanced photocatalytic activity was proposed.
The variation of the transformation-mediated deformation behavior with microstructural changes in CuZr-based bulk metallic glass composites is investigated. With increasing crystalline volume fraction, the deformation mechanism gradually changes from a shear-banding dominated process as evidenced by a chaotic serrated flow behavior, to being governed by a martensitic transformation with a pronounced elastic-plastic stage, resulting in different plastic deformations evolving into a self-organized critical state characterized by the power-law distribution of shear avalanches. This is reflected in the stress-strain curves by a single-to-“double”-to-“triple”-double yielding transition and by different mechanical properties with different serrated flow characteristics, which are interpreted based on the microstructural evolutions and a fundamental energy theorem. Our results can assist in understanding deformation behaviors for high-performance metastable alloys
Microstructures and mechanical properties of as-cast Cu47.5Zr47.5Al5 bulk metallic glass composites are optimized by appropriate remelting treatment of master alloys. With increasing remelting time, the alloys exhibit homogenized size and distribution of in situ formed B2 CuZr crystals. Pronounced tensile ductility of ∼13.6% and work-hardening ability are obtained for the composite with optimized microstructure. The effect of remelting treatment is attributed to the suppressed heterogeneous nucleation and growth of the crystalline phase from undercooled liquid, which may originate from the dissolution of oxides and nitrides as well as from the micro-scale homogenization of the melt
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