We quantify the oceanic sink for anthropogenic carbon dioxide (CO2) over the period 1994 to 2007 by using observations from the global repeat hydrography program and contrasting them to observations from the 1990s. Using a linear regression–based method, we find a global increase in the anthropogenic CO2inventory of 34 ± 4 petagrams of carbon (Pg C) between 1994 and 2007. This is equivalent to an average uptake rate of 2.6 ± 0.3 Pg C year−1and represents 31 ± 4% of the global anthropogenic CO2emissions over this period. Although this global ocean sink estimate is consistent with the expectation of the ocean uptake having increased in proportion to the rise in atmospheric CO2, substantial regional differences in storage rate are found, likely owing to climate variability–driven changes in ocean circulation.

Abstract. Version 2 of the Global Ocean Data Analysis Project (GLODAPv2) data product is composed of data from 724 scientific cruises covering the global ocean. It includes data assembled during the previous efforts GLODAPv1.1 (Global Ocean Data Analysis Project version 1.1) in 2004, CARINA (CARbon IN the Atlantic) in 2009/2010, and PACIFICA (PACIFic ocean Interior CArbon) in 2013, as well as data from an additional 168 cruises. Data for 12 core variables (salinity, oxygen, nitrate, silicate, phosphate, dissolved inorganic carbon, total alkalinity, pH, CFC-11, CFC-12, CFC-113, and CCl4) have been subjected to extensive quality control, including systematic evaluation of bias. The data are available in two formats: (i) as submitted but updated to WOCE exchange format and (ii) as a merged and internally consistent data product. In the latter, adjustments have been applied to remove significant biases, respecting occurrences of any known or likely time trends or variations. Adjustments applied by previous efforts were re-evaluated. Hence, GLODAPv2 is not a simple merging of previous products with some new data added but a unique, internally consistent data product. This compiled and adjusted data product is believed to be consistent to better than 0.005 in salinity, 1 % in oxygen, 2 % in nitrate, 2 % in silicate, 2 % in phosphate, 4 µmol kg−1 in dissolved inorganic carbon, 6 µmol kg−1 in total alkalinity, 0.005 in pH, and 5 % for the halogenated transient tracers.The original data and their documentation and doi codes are available at the Carbon Dioxide Information Analysis Center (http://cdiac.ornl.gov/oceans/GLODAPv2/). This site also provides access to the calibrated data product, which is provided as a single global file or four regional ones – the Arctic, Atlantic, Indian, and Pacific oceans – under the doi:10.3334/CDIAC/OTG.NDP093_GLODAPv2. The product files also include significant ancillary and approximated data. These were obtained by interpolation of, or calculation from, measured data. This paper documents the GLODAPv2 methods and products and includes a broad overview of the secondary quality control results. The magnitude of and reasoning behind each adjustment is available on a per-cruise and per-variable basis in the online Adjustment Table.

Abstract. Accurate assessment of anthropogenic carbon dioxide (CO 2 ) emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere is important to better understand the global carbon cycle, support the development of climate policies, and project future climate change. Here we describe data sets and a methodology to quantify all major components of the global carbon budget, including their uncertainties, based on the combination of a range of data, algorithms, statistics, and model estimates and their interpretation by a broad scientific community. We discuss changes compared to previous estimates as well as consistency within and among components, alongside methodology and data limitations. CO 2 emissions from fossil fuels and industry (E FF ) are based on energy statistics and cement production data, while emissions from land-use change (E LUC ), mainly deforestation, are based on combined evidence from land-cover-change data, fire activity associated with deforestation, and models. The global atmospheric CO 2 concentration is measured directly and its rate of growth (G ATM ) is computed from the annual changes in concentration. The mean ocean CO 2 sink (S OCEAN ) is based on observations from the 1990s, while the annual anomalies and trends are estimated with ocean models. The variability in S OCEAN is evaluated with data products based on surveys of ocean CO 2 measurements. The global residual terrestrial CO 2 sink (S LAND ) is estimated by the difference of the other terms of the global carbon budget and compared to results of independent dynamic global vegetation models forced by observed climate, CO 2 , and land-cover change (some including nitrogen-carbon interactions). We compare the mean land and ocean fluxes and their variability to estimates from three atmospheric inverse methods for three broad latitude bands. All uncertainties are reported as ±1σ , reflecting the current capacity to characterise the annual estimates of each component of the global carbon budget. For the last decade available (2005)(2006)(2007)(2008)(2009)(2010)(2011)(2012)(2013)(2014), E FF was 9.0 ± 0.5 GtC yr −1 , E LUC was 0.9 ± 0.5 GtC yr −1 , G ATM was 4.4 ± 0.1 GtC yr −1 , S OCEAN was 2.6 ± 0.5 GtC yr −1 , and S LAND was 3.0 ± 0.8 GtC yr −1 . For the year 2014 alone, E FF grew to 9.8 ± 0.5 GtC yr −1 , 0.6 % above 2013, continuing the growth trend in these emissions, albeit at a slower rate compared to the average growth of 2.2 % yr −1 that took place during 2005-2014. Also, for 2014, E LUC was 1.1 ± 0.5 GtC yr −1 , G ATM was 3.9 ± 0.2 GtC yr −1 , S OCEAN was 2.9 ± 0.5 GtC yr −1 , and S LAND was 4.1 ± 0.9 GtC yr −1 . G ATM was lower in 2014 compared to the past decade (2005)(2006)(2007)(2008)(2009)(2010)(2011)(2012)(2013)(2014), reflecting a larger S LAND for that year. The global atmospheric CO 2 concentration reached 397.15 ± 0.10 ppm averaged over 2014. For 2015, preliminary data indicate that the growth in E FF will be near or slightly below zero, with a projection of −0.6 [range of −1.6 to +0....

Abstract. We present a mapped climatology (GLODAPv2.2016b) of ocean biogeochemical variables based on the new GLODAP version 2 data product (Olsen et al., 2016; Key et al., 2015), which covers all ocean basins over the years 1972 to 2013. The quality-controlled and internally consistent GLODAPv2 was used to create global 1°  ×  1° mapped climatologies of salinity, temperature, oxygen, nitrate, phosphate, silicate, total dissolved inorganic carbon (TCO2), total alkalinity (TAlk), pH, and CaCO3 saturation states using the Data-Interpolating Variational Analysis (DIVA) mapping method. Improving on maps based on an earlier but similar dataset, GLODAPv1.1, this climatology also covers the Arctic Ocean. Climatologies were created for 33 standard depth surfaces. The conceivably confounding temporal trends in TCO2 and pH due to anthropogenic influence were removed prior to mapping by normalizing these data to the year 2002 using first-order calculations of anthropogenic carbon accumulation rates. We additionally provide maps of accumulated anthropogenic carbon in the year 2002 and of preindustrial TCO2. For all parameters, all data from the full 1972–2013 period were used, including data that did not receive full secondary quality control. The GLODAPv2.2016b global 1°  ×  1° mapped climatologies, including error fields and ancillary information, are available at the GLODAPv2 web page at the Carbon Dioxide Information Analysis Center (CDIAC; doi:10.3334/CDIAC/OTG.NDP093_GLODAPv2).

The decadal mean circulation in the northern North Atlantic was assessed for the early 21st century from repeated ship-based measurements along the Greenland-Portugal OVIDE line, from satellite altimetry and from earlier reported transports across 59.5°N and at the Greenland-Scotland sills. The remarkable quantitative agreement between all data sets allowed us to draw circulation pathways with a high level of confidence. The North Atlantic Current (NAC) system is composed of three main branches, referred to as the northern, central and southern branches, which were traced from the Mid-Atlantic Ridge (MAR), to the Irminger Sea, the Greenland-Scotland Ridge and the subtropical gyre. At OVIDE, the northern and central branches of the NAC fill the whole water column and their top-to-bottom integrated transports were estimated at 11.0 ± 3 Sv and 14.2 ± 6.4 Sv (1 Sv = 106 m3 s-1), respectively. Those two branches feed the cyclonic circulation in the Iceland Basin and the flow over the Reykjanes Ridge into the Irminger Sea. This cross-ridge flow was estimated at 11.3 ± 4.2 Sv westward, north of 58.5°N. The southern NAC branch is strongly surface-intensified and most of its top-to-bottom integrated transport, estimated at 16.6 ± 2 Sv, is found in the upper layer. It is composed of two parts: the northern part contributes to the flow over the Rockall Plateau and through the Rockall Trough towards the Iceland-Scotland Ridge; the southern part feeds the anticyclonic circulation towards the subtropical gyre. Summing over the three NAC branches, the top-to-bottom transport of the NAC across OVIDE was estimated at 41.8 ± 3.7 Sv.

International audienceWe discuss the distributions and transports of the main water masses in the North Atlantic Subpolar Gyre (NASPG) for the mean of the period 2002–2010 (OVIDE sections 2002–2010 every other year), as well as the inter-annual variability of the water mass structure from 1997 (4x and METEOR sections) to 2010. The water mass structure of the NASPG, quantitatively assessed by means of an Optimum MultiParameter analysis (with 14 water masses), was combined with the velocity fields resulting from previous studies using inverse models to obtain the water mass volume transports. We also evaluate the relative contribution to the Atlantic Meridional Overturning Circulation (AMOC) of the main water masses characterizing the NASPG, identifying the water masses that contribute to the AMOC variability. The reduction of the magnitude of the upper limb of the AMOC between 1997 and the 2000s is associated with the reduction in the northward transport of the Central Waters. This reduction of the northward flow of the AMOC is partially compensated by the reduction of the southward flow of the lower limb of the AMOC, associated with the decrease in the transports of Polar Intermediate Water and Subpolar Mode Water (SPMW) in the Irminger Basin. We also decompose the flow over the Reykjanes Ridge from the East North Atlantic Basin to the Irminger Basin (9.4 ± 4.7 Sv) into the contributions of the Central Waters (2.1 ± 1.8 Sv), Labrador Sea Water (LSW, 2.4 ± 2.0 Sv), Subarctic Intermediate Water (SAIW, 4.0 ± 0.5 Sv) and Iceland–Scotland Overflow Water (ISOW, 0.9 ± 0.9 Sv). Once LSW and ISOW cross over the Reykjanes Ridge, favoured by the strong mixing around it, they leave the Irminger Basin through the deep-to-bottom levels. The results also give insights into the water mass transformations within the NASPG, such as the contribution of the Central Waters and SAIW to the formation of the different varieties of SPMW due to air–sea interaction

Abstract.A well-documented, publicly available, global data set of surface ocean carbon dioxide (CO 2 ) parameters has been called for by international groups for nearly two decades. The Surface Ocean CO 2 Atlas (SOCAT) project was initiated by the international marine carbon science community in 2007 with the aim of providing a comprehensive, publicly available, regularly updated, global data set of marine surface CO 2 , which had been subject to quality control (QC). Many additional CO 2 data, not yet made public via the Carbon Dioxide Information Analysis Center (CDIAC), were retrieved from data originators, public websites and other data centres. All data were put in a uniform format following a strict protocol. Quality control was carried out according to clearly defined criteria. Regional specialists performed the quality control, using state-of-the-art web-based tools, specially developed for accomplishing this global team effort. SOCAT version 1.5 was made public in September 2011 and holds 6.3 million quality controlled surface CO 2 data points from the global oceans and coastal seas, spanning four decades . Three types of data products are available: individual cruise files, a merged complete data set and gridded products. With the rapid expansion of marine CO 2 data collection and the importance of quantifying net global oceanic CO 2 uptake and its changes, sustained data synthesis and data access are priorities. Data coverage MotivationThe net absorption of CO 2 by the oceans, caused by rising atmospheric CO 2 concentrations since the industrial revolution, has been responsible for removing CO 2 equivalent to approximately 50 % of the fossil fuel and cement manufacturing emissions or about 30 % of the total anthropogenic emissions, including land use change (Sabine et al., 2004). Because of the availability of the carbonate ion, an important species of the dissolved inorganic carbon pool, and carbonate sediments, the oceans have a tremendous CO 2 uptake capacity and will, on timescales of ten to hundred thousand years, absorb all but a small fraction of the fossil CO 2 that has been and will be emitted (Archer et al., 1997). Meanwhile the changes in ocean CO 2 uptake, relying on factors such as ocean circulation and biology, will be among the decisive factors for the evolution of future atmospheric CO 2 concentrations and climate development (e.g., Friedlingstein et al., 2006;Riebesell et al., 2009). Presently there are two types of globally coordinated efforts that seek to resolve the dynamics of ocean CO 2 uptake through observations: repeat hydrography and surface ocean CO 2 observations (Gruber et al., 2010;Sabine et al., 2010). While repeat hydrography aims to assess variations in the ocean inventory of CO 2 on decadal timescales, surface ocean observations may resolve variations on seasonal to interannual timescales due to the higher sampling frequency. This high sampling frequency has been made possible by the advent of autonomous instruments and sensors for the nearcontinuous determination o...

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