Using inorganic carbon measurements from an international survey effort in the 1990s and a tracer based separation technique, we estimate a global oceanic anthropogenic CO 2 sink for the period from 1800 to 1994 of 118±19 Pg C. The oceanic sink accounts for ~48% of the total fossil fuel and cement manufacturing emissions, implying that the terrestrial biosphere was a net source of CO 2 to the atmosphere of about 39±28 Pg C for this period. The current fraction of total anthropogenic CO 2 emissions stored in the ocean appears to be about one third of the long term potential.

The global ocean is a significant sink for anthropogenic carbon (C_ant), absorbing roughly a third of human CO₂ emitted over the industrial period. Robust estimates of the magnitude and variability of the storage and distribution of C_ant in the ocean are therefore important for understanding the human impact on climate. In this synthesis we review observational and model-based estimates of the storage and transport of C_ant in the ocean. We pay particular attention to the uncertainties and potential biases inherent in different inference schemes. On a global scale, three data-based estimates of the distribution and inventory of C_ant are now available. While the inventories are found to agree within their uncertainty, there are considerable differences in the spatial distribution. We also present a review of the progress made in the application of inverse and data assimilation techniques which combine ocean interior estimates of C_ant with numerical ocean circulation models. Such methods are especially useful for estimating the air–sea flux and interior transport of C_ant, quantities that are otherwise difficult to observe directly. However, the results are found to be highly dependent on modeled circulation, with the spread due to different ocean models at least as large as that from the different observational methods used to estimate C_ant. Our review also highlights the importance of repeat measurements of hydrographic and biogeochemical parameters to estimate the storage of C_ant on decadal timescales in the presence of the variability in circulation that is neglected by other approaches. Data-based C_ant estimates provide important constraints on forward ocean models, which exhibit both broad similarities and regional errors relative to the observational fields. A compilation of inventories of C_ant gives us a "best" estimate of the global ocean inventory of anthropogenic carbon in 2010 of 155 ± 31 PgC (±20% uncertainty). This estimate includes a broad range of values, suggesting that a combination of approaches is necessary in order to achieve a robust quantification of the ocean sink of anthropogenic CO₂

The decadal mean circulation in the northern North Atlantic was assessed for the early 21st century from repeated ship-based measurements along the Greenland-Portugal OVIDE line, from satellite altimetry and from earlier reported transports across 59.5°N and at the Greenland-Scotland sills. The remarkable quantitative agreement between all data sets allowed us to draw circulation pathways with a high level of confidence. The North Atlantic Current (NAC) system is composed of three main branches, referred to as the northern, central and southern branches, which were traced from the Mid-Atlantic Ridge (MAR), to the Irminger Sea, the Greenland-Scotland Ridge and the subtropical gyre. At OVIDE, the northern and central branches of the NAC fill the whole water column and their top-to-bottom integrated transports were estimated at 11.0 ± 3 Sv and 14.2 ± 6.4 Sv (1 Sv = 106 m3 s-1), respectively. Those two branches feed the cyclonic circulation in the Iceland Basin and the flow over the Reykjanes Ridge into the Irminger Sea. This cross-ridge flow was estimated at 11.3 ± 4.2 Sv westward, north of 58.5°N. The southern NAC branch is strongly surface-intensified and most of its top-to-bottom integrated transport, estimated at 16.6 ± 2 Sv, is found in the upper layer. It is composed of two parts: the northern part contributes to the flow over the Rockall Plateau and through the Rockall Trough towards the Iceland-Scotland Ridge; the southern part feeds the anticyclonic circulation towards the subtropical gyre. Summing over the three NAC branches, the top-to-bottom transport of the NAC across OVIDE was estimated at 41.8 ± 3.7 Sv.

International audienceWe discuss the distributions and transports of the main water masses in the North Atlantic Subpolar Gyre (NASPG) for the mean of the period 2002–2010 (OVIDE sections 2002–2010 every other year), as well as the inter-annual variability of the water mass structure from 1997 (4x and METEOR sections) to 2010. The water mass structure of the NASPG, quantitatively assessed by means of an Optimum MultiParameter analysis (with 14 water masses), was combined with the velocity fields resulting from previous studies using inverse models to obtain the water mass volume transports. We also evaluate the relative contribution to the Atlantic Meridional Overturning Circulation (AMOC) of the main water masses characterizing the NASPG, identifying the water masses that contribute to the AMOC variability. The reduction of the magnitude of the upper limb of the AMOC between 1997 and the 2000s is associated with the reduction in the northward transport of the Central Waters. This reduction of the northward flow of the AMOC is partially compensated by the reduction of the southward flow of the lower limb of the AMOC, associated with the decrease in the transports of Polar Intermediate Water and Subpolar Mode Water (SPMW) in the Irminger Basin. We also decompose the flow over the Reykjanes Ridge from the East North Atlantic Basin to the Irminger Basin (9.4 ± 4.7 Sv) into the contributions of the Central Waters (2.1 ± 1.8 Sv), Labrador Sea Water (LSW, 2.4 ± 2.0 Sv), Subarctic Intermediate Water (SAIW, 4.0 ± 0.5 Sv) and Iceland–Scotland Overflow Water (ISOW, 0.9 ± 0.9 Sv). Once LSW and ISOW cross over the Reykjanes Ridge, favoured by the strong mixing around it, they leave the Irminger Basin through the deep-to-bottom levels. The results also give insights into the water mass transformations within the NASPG, such as the contribution of the Central Waters and SAIW to the formation of the different varieties of SPMW due to air–sea interaction

Abstract.A well-documented, publicly available, global data set of surface ocean carbon dioxide (CO 2 ) parameters has been called for by international groups for nearly two decades. The Surface Ocean CO 2 Atlas (SOCAT) project was initiated by the international marine carbon science community in 2007 with the aim of providing a comprehensive, publicly available, regularly updated, global data set of marine surface CO 2 , which had been subject to quality control (QC). Many additional CO 2 data, not yet made public via the Carbon Dioxide Information Analysis Center (CDIAC), were retrieved from data originators, public websites and other data centres. All data were put in a uniform format following a strict protocol. Quality control was carried out according to clearly defined criteria. Regional specialists performed the quality control, using state-of-the-art web-based tools, specially developed for accomplishing this global team effort. SOCAT version 1.5 was made public in September 2011 and holds 6.3 million quality controlled surface CO 2 data points from the global oceans and coastal seas, spanning four decades . Three types of data products are available: individual cruise files, a merged complete data set and gridded products. With the rapid expansion of marine CO 2 data collection and the importance of quantifying net global oceanic CO 2 uptake and its changes, sustained data synthesis and data access are priorities. Data coverage MotivationThe net absorption of CO 2 by the oceans, caused by rising atmospheric CO 2 concentrations since the industrial revolution, has been responsible for removing CO 2 equivalent to approximately 50 % of the fossil fuel and cement manufacturing emissions or about 30 % of the total anthropogenic emissions, including land use change (Sabine et al., 2004). Because of the availability of the carbonate ion, an important species of the dissolved inorganic carbon pool, and carbonate sediments, the oceans have a tremendous CO 2 uptake capacity and will, on timescales of ten to hundred thousand years, absorb all but a small fraction of the fossil CO 2 that has been and will be emitted (Archer et al., 1997). Meanwhile the changes in ocean CO 2 uptake, relying on factors such as ocean circulation and biology, will be among the decisive factors for the evolution of future atmospheric CO 2 concentrations and climate development (e.g., Friedlingstein et al., 2006;Riebesell et al., 2009). Presently there are two types of globally coordinated efforts that seek to resolve the dynamics of ocean CO 2 uptake through observations: repeat hydrography and surface ocean CO 2 observations (Gruber et al., 2010;Sabine et al., 2010). While repeat hydrography aims to assess variations in the ocean inventory of CO 2 on decadal timescales, surface ocean observations may resolve variations on seasonal to interannual timescales due to the higher sampling frequency. This high sampling frequency has been made possible by the advent of autonomous instruments and sensors for the nearcontinuous determination o...

Abstract. The Atlantic and Arctic Oceans are critical components of the global carbon cycle. Here we quantify the net sea–air CO2 flux, for the first time, across different methodologies for consistent time and space scales for the Atlantic and Arctic basins. We present the long-term mean, seasonal cycle, interannual variability and trends in sea–air CO2 flux for the period 1990 to 2009, and assign an uncertainty to each. We use regional cuts from global observations and modeling products, specifically a pCO2-based CO2 flux climatology, flux estimates from the inversion of oceanic and atmospheric data, and results from six ocean biogeochemical models. Additionally, we use basin-wide flux estimates from surface ocean pCO2 observations based on two distinct methodologies. Our estimate of the contemporary sea–air flux of CO2 (sum of anthropogenic and natural components) by the Atlantic between 40° S and 79° N is −0.49 ± 0.05 Pg C yr−1, and by the Arctic it is −0.12 ± 0.06 Pg C yr−1, leading to a combined sea–air flux of −0.61 ± 0.06 Pg C yr−1 for the two decades (negative reflects ocean uptake). We do find broad agreement amongst methodologies with respect to the seasonal cycle in the subtropics of both hemispheres, but not elsewhere. Agreement with respect to detailed signals of interannual variability is poor, and correlations to the North Atlantic Oscillation are weaker in the North Atlantic and Arctic than in the equatorial region and southern subtropics. Linear trends for 1995 to 2009 indicate increased uptake and generally correspond between methodologies in the North Atlantic, but there is disagreement amongst methodologies in the equatorial region and southern subtropics.

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Uptake of atmospheric carbon dioxide in the subpolar North Atlantic Ocean declined rapidly between 1990 and 2006. This reduction in carbon dioxide uptake was related to warming at the sea surface, which-according to model simulations-coincided with a reduction in the Atlantic meridional overturning circulation. The extent to which the slowdown of this circulation system-which transports warm surface waters to the northern high latitudes, and cool deep waters south-contributed to the reduction in carbon uptake has remained uncertain. Here, we use data on the oceanic transport of volume, heat and carbon dioxide to track carbon dioxide uptake in the subtropical and subpolar regions of the North Atlantic Ocean over the past two decades. We separate anthropogenic carbon from natural carbon by assuming that the latter corresponds to a pre-industrial atmosphere, whereas the remaining is anthropogenic. We find that the uptake of anthropogenic carbon dioxide-released by human activities-occurred almost exclusively in the subtropical gyre. In contrast, natural carbon dioxide uptake-which results from natural Earth system processes-dominated in the subpolar gyre. We attribute the weakening of contemporary carbon dioxide uptake in the subpolar North Atlantic to a reduction in the natural component. We show that the slowdown of the meridional overturning circulation was largely responsible for the reduction in carbon uptake, through a reduction of oceanic heat loss to the atmosphere, and for the concomitant decline in anthropogenic CO 2 storage in subpolar waters. 2. However, air-sea CO 2 uptake in the North Atlantic is not necessarily predominantly anthropogenic 3, 4. In fact, air-sea CO 2 fluxes in the North Atlantic result from anthropogenic forcing and progressive northward cooling of the upper limb of the meridional overturning circulation