Cyclopentanone reacts with arylidenemalononitriles 1a–c to give dihydro‐4,6‐indenedicarbonitriles 5a–c. Similarly, the diethyl dihydro‐4,6‐indenedicarboxylate derivative 6 is formed when treating ethyl α‐cyanocinnamate (1d) with cyclopentanone. Cyclopenta[b]pyrans 5a–c are obtained from the reaction of diarylidene derivatives of cyclopentanone with malononitrile.
Abstract:In this work, a supercritical carbon dioxide assembly was successfully constructed for dyeing Nylon6 fabric. Primary experiments were carried out to confirm the possibility of bringing the dyeing up to factory scale. A series of disperse azo dyes with potential antibacterial activity were applied to dye the fabric under our study in supercritical carbon dioxide (scCO2). The factors affecting the dyeing conditions (i.e., dye concentration, time, temperature and pressure) and functional properties were discussed and compared with those in aqueous dyeing. The comparison revealed that elimination of auxiliary chemicals such as salt, carrier or dispersing agent has no diverse effect on dyeing. The color strength of the dyed fabric evaluated by using K/S measurements increased by increasing dye concentration from 2% to 6% owf. (on weight of fabric). The nylon6 fabrics dyed in supercritical carbon dioxide have good fastness properties, and especially light fastness compared with conventional exhaustion dyeing. Antibacterial activity of the dyed samples under supercritical conditions was evaluated and the results showed excellent antibacterial efficiency.
In this work, new hydrazonopropanenitrile
dyes with potential antibacterial
activity were applied for dyeing polyester fabrics with supercritical
carbon dioxide as a dyeing medium. The experimental conditions were
optimized to obtain both visibly and spectrophotometrically uniform
dye uptakes in the fabric. Raman microspectroscopy firmly indicated
the dye uptake through all layers of the fabric. The color strength
of the fabric was evaluated by K/S measurements and proved to be higher
than those of conventional dyeing. The fastness properties of the
dyed fabric were evaluated and found to give excellent results. The
antibacterial test was performed according to the AA-TCC method, and
the results were recorded.
Benzo[b]pyrans, naphtho[1,2-b]pyrans, naphtho[2,1-b]pyrans, pyrano[3,2-h]quinolines, and pyrano[3,2-c]quinolines were synthesized by the reaction of cinnamonitriles with phenols, naphthols, 8-hydroxyquinoline, and 1-methyl-4-hydroxy-2-quinoline.
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