Pure Ni and nickel matrix composite electrocoatings containing micron-and nano-SiC particles (1 lm and 20 nm respectively) were produced under direct and pulse current conditions from an additive-free Watts type bath. The effect of the particle size, codeposition percentage of SiC and type of imposed current on the microhardness as well as on the microstructure of the electrodeposits were investigated. Ni/SiC composite deposits prepared under either direct or pulse current conditions exhibited a considerable strengthening effect with respect to pure Ni coatings. The improved hardness of composite coatings was associated to specific structural modifications of Ni crystallites provoked by the adsorption of H + on the surface of SiC particles, thus leading to a (211) texture mode of Ni crystal growth. Pulse electrodeposition significantly improved the hardness of the Ni/SiC composite coatings, especially at low duty cycles, in which grain refinement and higher SiC incorporation (vol. %) was achieved. The enhanced hardness of Ni/nano-SiC deposits, as compared to Ni/micron-SiC composites, was attributed to the increasing values of the number density of embedded SiC particles in the nickel matrix with decreasing particle size. In addition, the observed hardening effects of the SiC particles might be associated to the different embedding mechanisms of the particles, which could be characterized as inter-crystalline for micron-SiC and partially intracrystalline for nano-SiC particles.

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In this study, the synthesis of smart, polymerically embedded titanium dioxide (TiO2) nanoparticles aimed to exhibit photo-induced anticancer properties under visible light irradiation is investigated. The TiO2 nanoparticles were prepared by utilizing the sol gel method with different dopants, including nitrogen (N-doped), iron (Fe-doped), and nitrogen and iron (Fe,N-doped). The dopants were embedded in an interpenetrating (IP) network microgel synthesized by stimuli responsive poly (N-Isopropylacrylamide-co-polyacrylicacid)–pNipam-co-PAA forming composite particles. All the types of produced particles were characterized by X-ray powder diffraction, micro-Raman, Fourier-transform infrared, X-ray photoelectron, ultra-violet-visible spectroscopy, Field Emission Scanning Electron, Transmission Electron microscopy, and Dynamic Light Scattering techniques. The experimental findings indicate that the doped TiO2 nanoparticles were successfully embedded in the microgel. The N-doped TiO2 nano-powders and composite particles exhibit the best photocatalytic degradation of the pollutant methylene blue under visible light irradiation. Similarly, the highly malignant MDA-MB-231 breast cancer epithelial cells were susceptible to the inhibition of cell proliferation at visible light, especially in the presence of N-doped powders and composites, compared to the non-metastatic MCF-7 cells, which were not affected.

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