The transfer of heat
energy in organic semiconductors (OSCs) plays
an important role in advancing the applications of organic electronics,
especially for lifetime issues. However, compared with crystalline
inorganic semiconductors, the thermal transport of OSCs is less efficient
and a relevant understanding is very limited. In this contribution,
we show that the heat conduction of OSCs can be enhanced by blending
with a “commodity” insulator (both thermal and electrical).
PC71BM, a well-known electron transporter but poor thermal
conductor, was selected as the host OSC material. The blending of
a small amount of polystyrene (PS), a commonly used insulating polymer,
can facilitate the heat transfer of PC71BM films, as substantiated
by the scanning photothermal deflection technique and an infrared
thermal camera. The phase thermodynamics of PC71BM/PS blends
indicates that the efficient heat transfer preferably occurs in the
OSC/insulator blends with better intimate mixing, where isolated PC71BM domains can be effectively bridged by PS that thread through
the regions. The applicability of this approach can be observed in
blends with another host materialITIC. This work provides
a facile strategy for designing thermally durable organic electronic
devices.