Synthesis of magnolol-derived bisphosphate for fabrication of bismaleimide resins with intrinsic anti-flammability and smoke suppression

Enhanced thermal and porous properties of double-decker-shaped polyhedral silsesquioxane-bismaleimide (DDSQ-BMI) nanocomposites for high-performance CO2 storage and supercapacitors

“…Extensive research has been performed to increase the hardness of BMI through copolymerization or homopolymerization with substances, such as cyanate esters, epoxy resins and aromatic amines, and a compromise is made between the required mechanical properties and thermal resistance of the modified BMI. 28,29 There are also some challenges related to the stability of POPs, which may limit their long-term use in certain applications, and thus, there have been numerous efforts to increase their stability and optimize their properties. [30][31][32][33] In pursuit of improved thermal properties for BMI derivatives, in our previous study, we proposed the incorporation of inorganic nanoparticles such as double-decker-shaped polyhedral silsesquioxane (DDSQ).…”

Bioinspired Natural Magnolol-Based Adhesive with Strong Adhesion and Antibacterial Properties for Application in Wet and Dry Environments

“…Wacker et al prepared a thermoset network platform from magnolol. Guo successfully synthesized magnolol-derived bisphosphonates (MBDPP) for flame-retardant materials by a substitution reaction between magnolol and diphenylphosphoryl chloride. Jian − research group has also systematically researched the application of magnolol as a material and developed a series of sustainable biobased epoxy resins as a substitute for petroleum-based resins.…”

Biomass Modifiers for Low Dielectric Bismaleimides at High-Frequency

“…The allyl group can react with the double bonds of BMIs to enhance the brittleness of the materials, while the hydroxyl group can be functionalized by fluoro-containing groups. Currently, some investigations on the bismaleimide resins derived from biomass have been done, while the performance of these resins is unsatisfactory. − In this contribution, we synthesized the fluoro-containing monomers M1 and M2 (structures shown in Scheme ). The copolymerization of commercial BMI (4,4′-bismaleimidodiphenylmethane) with M1 or M2 in different molar ratios generated a series of cured BMIs.…”