“…It is well-known that AZO thin films are highly textured with the c-axis perpendicular to the substrate surface, especially in the (0 0 2) orientation. This (0 0 2) preferred orientation is due to the minimal surface energy, which the hexagonal structure (c-plane to the ZnO crystallites) corresponds to the densest packed plane [28][29][30]. If Al 3 þ ions only substitute Zn 2 þ ions, the lattice parameter of AZO crystals decreases and the (0 0 2) peak shifts to higher 2y value due to the smaller radius of Al 3 þ ions (0.53Å) compared to Zn 2 þ ions (0.75Å) [28].…”