An investigation is made of doping of GaAs and InxGa1−xAs films with Sn and Te. The distribution of donors and acceptors, their sum and difference, and the compensation coefficient k = Na/Nd are demonstrated as functions of growth temperature, composition of the liquid phase and substrate orientation. It is shown that Nd, Nd — Na, Nd — Na increase for Te doped films and decrease for Sn doped films when the temperature is lowered. The same parameters increase for Sn doped and decrease for Te doped films with an increase of the indium part in the liquid phase. The inequalities K(111)B (Nd + Na)(111)A were observed for all investigated temperatures and liquid phase compositions.