Migration-enhanced epitaxy (MEE) has been successfully employed to grow epitaxial films of the ternary compound CuInSe2 on (001) GaAs that exhibit distinct coexisting domains of both a nonequilibrium crystallographic structure characterized by CuAu (CA) cation ordering, and the compound’s equilibrium chalcopyrite structure. X-ray diffraction, transmission electron diffraction, and Raman scattering data provide evidence for this structural polytype. Distinctive signatures of the CA polytype are found in the data from each of these methods, and their analyses are consistent with assignment of this crystallographic structure to the P4̄m2 space group. This structure is found to preferentially segregate into domains that constitute a distinct metastable phase, which may be stabilized by surface kinetic effects favored by the MEE growth process.
Die Kristallstruktur von LiInTe2 im Chalcopyrit‐Typ wurde aus Einkristalldaten bestimmt (a) = 639,8(2) pm, c = 1246,0(4) pm, Raumgruppe I 42d (Nr. 122), x(Te) = 0,2441(1), 154 hkl, R = 0,02). Die Abstände Li–Te sind mit 272,5 pm größer, die Abstände InTe mit 276,8 pm gleich den berechneten Werten. Die Struktur wird im Zusammenhang mit analogen Cu‐ und Ag‐Verbindungen diskutiert.
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