Fabric phase sorptive extraction for the fast isolation of sulfonamides residues from raw milk followed by high performance liquid chromatography with ultraviolet detection

Karageorgou, Eftychia; Manousi, Natalia; Samanidou, Victoria; Kabir, Abuzar; Furton, Kenneth G.

doi:10.1016/j.foodchem.2015.09.060

Cited by 96 publications

(55 citation statements)

References 22 publications

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“…Other approaches include LLE [49], DLLME [50], as well as a modified QuEChERS extraction protocol that employed C18, MgSO 4 and PSA [50], SALLE combined with SPE [51], and a miniaturized SALLE protocol [52]. Interesting approaches include FPSE [60], GMeS microextraction [61], and mini-SAE [62]. Reported novel materials include a magnetic hyper cross-linked polystyrene composite [58] and a magnetic graphene-based composite [59] utilized in MSPE protocols and multi-template MIPs prepared by sol-gel synthesis utilized in a SPE protocol [56].…”

Section: Discussionmentioning

confidence: 99%

“…The proposed fabric sorbent could be applied directly into the untreated milk sample offering a simpler extraction protocol and higher recoveries. Furthermore, the fabric sorbent displayed high chemical and solvent stability that allows the use of the suitable extraction solvent for sample analysis with multiple chromatographic techniques [60]. The GMeS microextraction protocol was reported for the extraction of eight SAs from milk, egg, and water.…”

Section: Other Extraction Techniquesmentioning

confidence: 99%

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Food Sample Preparation for the Determination of Sulfonamides by High-Performance Liquid Chromatography: State-of-the-Art

et al. 2018

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Antibiotics are a common practice in veterinary medicine, mainly for therapeutic purposes. Sectors of application include livestock farming, aquacultures, and bee-keeping, where bacterial infections are frequent and can be economically damaging. However, antibiotics are usually administered in sub-therapeutic doses as prophylactic and growth promoting agents. Due to their excessive use, antibiotic residues can be present in foods of animal origin, which include meat, fish, milk, eggs, and honey, posing health risks to consumers. For this reason, authorities have set maximum residue limits (MRLs) of certain antibiotics in food matrices, while analytical methods for their determination have been developed. This work focuses on antibiotic extraction and determination, part of which was presented at the "1st Conference in Chemistry for Graduate, Postgraduate Students and PhD Candidates at the Aristotle University of Thessaloniki". Taking a step further, this paper is a review of the most recent sample preparation protocols applied for the extraction of sulfonamide antibiotics from food samples and their determination with high-performance liquid chromatography (HPLC), covering a five-year period.

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Section: Discussionmentioning

confidence: 99%

Section: Other Extraction Techniquesmentioning

confidence: 99%

Food Sample Preparation for the Determination of Sulfonamides by High-Performance Liquid Chromatography: State-of-the-Art

et al. 2018

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“…Designing the sol solution is the main step on the way to the development of a sol-gel sorbent due to the fact that its composition and the relative ratio of the constituents, define the porosity as well as the selectivity and specificity of the resulting sorbent [24]. For an effective sol-gel sorbent, the selection of the sol-gel active organic polymer, the inorganic or organically modified inorganic sol-gel precursor, the solvent/solvent system, the catalyst, the amount of water, as well as an appropriate relative molar ratio of the constituents must be considered.…”

Section: Preparation Of the Sol Solution For The Sol-gel Coating Processmentioning

confidence: 99%

“…Karageorgou et al [24] developed a simple FPSE-HPLC-UV method for the isolation of three sulfonamides, SMTH, SIX, and SDMX, from untreated milk samples. The highly polar sol-gel PEG coated on a cellulose substrate was used for the extraction of the selected sulfonamides.…”

Section: Applications Of Fabric Phase Sorptive Extractionmentioning

confidence: 99%

Fabric Sol–gel Phase Sorptive Extraction Technique: A Review

Kazantzi

Anthemidis

2017

Separations

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Since the introduction in 2014 of fabric phase sorptive extraction (FPSE) as a sample preparation technique, it has attracted the attention of many scientists working in the field of separation science. This novel sorbent extraction technique has successfully utilized the benefits of sol-gel derived hybrid sorbents and a plethora of fabric substrates, resulting in a highly efficient, sensitive and green sample pretreatment methodology. The proposed procedure is an easy and efficient pathway to extract target analytes from different matrices providing inherent advantages such as high sample loading capacity and short pretreatment time. The present review mainly focuses on the background and sol-gel chemistry for the preparation of new fabric sorbents as well as on the applications of FPSE for extracting target analytes, from the time that it was first introduced. New modes of FPSE including stir FPSE, stir-bar FPSE, dynamic FPSE, and automated on-line FPSE are also highlighted and commented upon in detail. FPSE has been effectively applied for the determination of various organic and inorganic analytes in different types of environmental and biological samples in high throughput analytical, environmental, and toxicological laboratories.

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“…Although FPSE has emerged as a major analytical sample preparation technique [26][27][28][29][30][31][32][33][34][35][36][37][38][39][40][41][42][43][44][45], the theory and principle of this simple, innovative and environment friendly technique is yet to be fully studied and understood. As such, the primary objective of the current project is to thoroughly study the theory and principle of fabric phase sorptive extraction.…”

Section: Introductionmentioning

confidence: 99%

Fabric Phase Sorptive Extraction Explained

Kabir¹,

Mesa²,

Jurmain³

et al. 2017

Preprint

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The theory and working principle of fabric phase sorptive extraction (FPSE) is presented that eloquently explains the mystery behind this new and powerful sample preparation technique. FPSE innovatively integrates the benefits of sol-gel coating technology and the rich surface chemistry of cellulose/polyester/fiberglass fabric, resulting in a microextraction device with very high sorbent loading in the form of an ultra-thin coating. This porous sorbent coating and the permeable substrate synergistically facilitate very fast extraction equilibrium. The flexibility of the FPSE device allows for direct insertion into original, unmodified samples of different origin. Strong chemical bonding between the sol-gel sorbent and the fabric substrate permits the exposure of FPSE devices to any organic solvent for analyte back-extraction/elution and to highly acidic or basic environments (pH 1-12) if required. A sol-gel derived sorbent, highly polar sol-gel poly(ethylene glycol) coating, was generated on cellulose substrates. Five cm 2 segments of these coated fabrics were used as the FPSE devices for sample preparation using direct immersion. An important class of environmental pollutants, substituted phenols, was used as model compounds to evaluate the extraction performance of FPSE. The high primary contact surface area (PCSA) of the FPSE device and porous structure of the sol-gel coatings resulted in very high sample capacities and incredible extraction sensitivities for both the compound classes in a relatively short period of time. Different extraction parameters were evaluated and optimized. The new extraction devices demonstrated part per trillion level detection limits for substitute phenols, a wide range of detection linearity, and good performance reproducibility.

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Fabric phase sorptive extraction for the fast isolation of sulfonamides residues from raw milk followed by high performance liquid chromatography with ultraviolet detection

Cited by 96 publications

References 22 publications

Food Sample Preparation for the Determination of Sulfonamides by High-Performance Liquid Chromatography: State-of-the-Art

Food Sample Preparation for the Determination of Sulfonamides by High-Performance Liquid Chromatography: State-of-the-Art

Fabric Sol–gel Phase Sorptive Extraction Technique: A Review

Fabric Phase Sorptive Extraction Explained

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