We studied the resistive memory switching in pulsed laser deposited amorphous LaHoO 3 (a-LHO) thin films for non-volatile resistive random access memory (RRAM) applications.Nonpolar resistive switching (RS) was achieved in Pt/a-LHO/Pt memory cells with all four possible RS modes (i.e., positive unipolar, positive bipolar, negative unipolar, and negative bipolar) having high R ON /R OFF ratios (in the range of ~10 4 -10 5 ) and non-overlapping switching voltages (set voltage, V ON ~ ± 3.6˗4.2 V and reset voltage, V OFF ~ ± 1.3˗1.6 V) with a small variation of about ± 5˗8%. X-ray photoelectron spectroscopic studies together with temperature dependent switching characteristics revealed the formation of metallic holmium (Ho 0 ) and oxygen vacancies (V O ) constituted conductive nanofilaments (CNFs) in the low resistance state (LRS). Detailed analysis of current-voltage characteristics further corroborated the formation of CNFs based on metal-like (Ohmic) conduction in LRS. Simmons-Schottky emission was found to be the dominant charge transport mechanism in the high resistance state.
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