The ultra-wideband (UWB) multi-input multi-output (MIMO) radar technique is playing a more and more important role in the application of through-wall detection because of its high resolution, lower antenna requirements, and efficient data capturing ability. This paper develops a novel UWB MIMO radar system using a stepped-frequency continuous-wave (SFCW) signal, which is designed to detect human targets behind the regular brick and concrete wall. In order to balance high range resolution and wall-penetration depth, a novel miniaturized Vivaldi antenna with desired bandwidth of 0.5–2.5 GHz was designed, simulated, manufactured, and successfully used in through-wall imaging. To suppress the artifacts in the focused image and reduce the computing complexity, the cross-correlation-based time domain back projection (CC-TDBP) algorithm was developed. In addition, a through-wall imaging model was established, based on which the effects of the wall on the refraction of electromagnetic (EM) waves and the reduction of velocity are compensated. Finally, different experiments were conducted for multiple stationary targets utilizing the designed radar system, and the improved BP-based algorithms are applied to focus the targets behind the wall more accurately. The reconstructed two-dimensional (2D) images illustrate that the designed MIMO radar system can successfully detect and image human targets in the air and behind the wall.

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Organocatalytic conjugate addition of malononitrile to conformationally restricted dienones has been studied. A series of chiral primary and tertiary amine catalysts were screened. A piperidine-based thiourea-tertiary amine was found to be the efficient catalyst. Chiral pyran derivatives were obtained in excellent yields and enantioselectivities via a cascade conjugate addition-intramolecular cyclization pathway. The reaction is remarkably different for the corresponding reaction of conformationally flexible dienones.

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The conjugate addition of cyclic 1,3-dicarbonyl compounds to β,γ-unsaturated α-keto-esters was studied using a series of chiral bifunctional organocatalysts. Takemoto's catalyst was found to be most efficient for this transformation. Excellent yields and good enantioselectivities were achieved for a variety of β,γ-unsaturated α-keto-esters and cyclic 1,3-dicarbonyl compounds. A bifunctional catalytic mechanism is proposed. The method provides a new asymmetric synthetic route for chiral courmarin derivatives.

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A novel metal-free catalytic annulation was developed through a Lewis base-catalyzed asymmetric allylic alkylation and the ensuing unprecedented asymmetric intramolecular acylcyanation of alkenes. This protocol provides a unique and facile access to prepare enantioenriched densely functionalized dihydronaphthoquinones accompanied by enantiomerically pure 3,3-disubstituted phthalides bearing quaternary carbon centers.