The solid electrolyte interphase (SEI), a passivation layer formed on electrodes, is critical to battery performance and durability. The inorganic components in SEI, including lithium carbonate (Li2CO3) and lithium fluoride (LiF), provide both mechanical and chemical protection, meanwhile control lithium ion transport. Although both Li2CO3 and LiF have relatively low ionic conductivity, we found, surprisingly, that the contact between Li2CO3 and LiF can promote space charge accumulation along their interfaces, which generates a higher ionic carrier concentration and significantly improves lithium ion transport and reduces electron leakage. The synergetic effect of the two inorganic components leads to high current efficiency and long cycle stability.
These two authors contributed equally to this work. The ability to manipulate antiferromagnetic (AF) moments is a key requirement for the emerging field of antiferromagnetic spintronics. Electrical switching of bi-state AF moments has been demonstrated in metallic AFs, CuMnAs and Mn 2 Au. 1-5 Recently, current-induced "saw-tooth" shaped Hall resistance was reported in Pt/NiO bilayers, 6-9 while its mechanism is under debate. Here, we report the first demonstration of convincing, non-decaying, steplike electrical switching of tri-state Néel order in Pt/-Fe 2 O 3 bilayers. Our experimental data, together with Monte-Carlo simulations, reveal the clear mechanism of the switching behavior of -Fe 2 O 3 Néel order among three stable states. We also show that the observed "saw-tooth" Hall resistance is due to an artifact of Pt, not AF switching, while the signature of AF switching is step-like Hall signals. This demonstration of electrical control of magnetic moments in AF insulator (AFI) films will greatly expand the scope of AF spintronics by leveraging the large family of AFIs.Spin-orbit torque (SOT) induced switching of ferromagnets (FM) by an adjacent heavy metal (HM) has raised wide interests in recently years, 10-12 where a charge current in the HM generates spins at the HM/FM interface via the spin Hall effect (SHE). AFs offer the advantage of no stray field, robustness against external field, THz response, and abundance of material
Understanding of the electrical conduction, that is, ionic and electronic conduction, through the solid electrolyte interphase (SEI) is critical to the design of durable lithium-ion batteries (LIBs) with high rate capability and long life. It is believed that an ideal SEI should not only be an ionic conductor, but also an electronic insulator. In this study, we present a theoretical design of an artificial SEI consisting of lithium fluoride (LiF) and lithium carbonate (Li2CO3) on a LIB anode based on a newly developed density functional theory (DFT) informed space charge model. We demonstrate that the migration of lattice Li ions from LiF phase to form Li interstitials in Li2CO3 is energetically favorable near the LiF/Li2CO3 interface. At equilibrium, this interfacial defect reaction establishes a space charge potential across the interface, which causes the accumulation of ionic carriers but the depletion of electronic carriers near the LiF/Li2CO3 interface. To utilize this space charge effect, we propose a computationally designed, nanostructured artificial SEI structure with high density of interfaces of LiF and Li2CO3 perpendicular to the electrode. On the basis of this structure, the influences of grain size and volume ratio of the two phases were studied. Our results reveal that reducing the grain size of Li2CO3 in the nanostructured composite can promote ionic carriers and increase the ionic conductivity through the composite SEI by orders of magnitude. At the same time, the electronic conductivity is reduced due to electron depletion near the LiF/Li2CO3 interface. Furthermore, an optimal volume fraction that ensures high ionic and low electronic conduction was predicted.
Low-damping magnetic materials have been widely used in microwave and spintronic applications because of their low energy loss and high sensitivity. While the Gilbert damping constant can reach 10−4 to 10−5 in some insulating ferromagnets, metallic ferromagnets generally have larger damping due to magnon scattering by conduction electrons. Meanwhile, low-damping metallic ferromagnets are desired for charge-based spintronic devices. Here, we report the growth of Co25Fe75 epitaxial films with excellent crystalline quality evident by the clear Laue oscillations and exceptionally narrow rocking curve in the X-ray diffraction scans as well as from scanning transmission electron microscopy. Remarkably, the Co25Fe75 epitaxial films exhibit a damping constant <1.4 × 10−3, which is comparable to the values for some high-quality Y3Fe5O12 films. This record low damping for metallic ferromagnets offers new opportunities for charge-based applications such as spin-transfer-torque-induced switching and magnetic oscillations.
This letter reports the modification of magnetism in a magnetic insulator Y 3 Fe 5 O 12 thin film by topological surface states (TSS) in an adjacent topological insulator Bi 2 Se 3 thin film. Ferromagnetic resonance measurements show that the TSS in Bi 2 Se 3 produces a perpendicular magnetic anisotropy, results in a decrease in the gyromagnetic ratio, and
The intercalation compounds are generally considered as ideal electrode materials for lithium-ion batteries thanks to their minimum volume expansion and fast lithium ion diffusion. However, cracking still occurs in those compounds and has been identified as one of the critical issues responsible for their capacity decay and short cycle life, although the diffusion-induced stress and volume expansion are much smaller than those in alloying-type electrodes. Here, we designed a thin-film model system that enables us to tailor the cation ordering in LiNi(0.5)Mn(1.5)O4 spinels and correlate the stress patterns, phase evolution, and cycle performances. Surprisingly, we found that distinct reaction paths cause negligible difference in the overall stress patterns but significantly different cracking behaviors and cycling performances: 95% capacity retention for disordered LiNi(0.5)Mn(1.5)O4 and 48% capacity retention for ordered LiNi(0.5)Mn(1.5)O4 after 2000 cycles. We were able to pinpoint that the extended solid-solution region with suppressed phase transformation attributed to the superior electrochemical performance of disordered spinel. This work envisions a strategy for rationally designing stable cathodes for lithium-ion batteries through engineering the atomic structure that extends the solid-solution region and suppresses phase transformation.
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