The solid electrolyte interphase (SEI), a passivation layer formed on electrodes, is critical to battery performance and durability. The inorganic components in SEI, including lithium carbonate (Li2CO3) and lithium fluoride (LiF), provide both mechanical and chemical protection, meanwhile control lithium ion transport. Although both Li2CO3 and LiF have relatively low ionic conductivity, we found, surprisingly, that the contact between Li2CO3 and LiF can promote space charge accumulation along their interfaces, which generates a higher ionic carrier concentration and significantly improves lithium ion transport and reduces electron leakage. The synergetic effect of the two inorganic components leads to high current efficiency and long cycle stability.

These two authors contributed equally to this work. The ability to manipulate antiferromagnetic (AF) moments is a key requirement for the emerging field of antiferromagnetic spintronics. Electrical switching of bi-state AF moments has been demonstrated in metallic AFs, CuMnAs and Mn 2 Au. 1-5 Recently, current-induced "saw-tooth" shaped Hall resistance was reported in Pt/NiO bilayers, 6-9 while its mechanism is under debate. Here, we report the first demonstration of convincing, non-decaying, steplike electrical switching of tri-state Néel order in Pt/-Fe 2 O 3 bilayers. Our experimental data, together with Monte-Carlo simulations, reveal the clear mechanism of the switching behavior of -Fe 2 O 3 Néel order among three stable states. We also show that the observed "saw-tooth" Hall resistance is due to an artifact of Pt, not AF switching, while the signature of AF switching is step-like Hall signals. This demonstration of electrical control of magnetic moments in AF insulator (AFI) films will greatly expand the scope of AF spintronics by leveraging the large family of AFIs.Spin-orbit torque (SOT) induced switching of ferromagnets (FM) by an adjacent heavy metal (HM) has raised wide interests in recently years, 10-12 where a charge current in the HM generates spins at the HM/FM interface via the spin Hall effect (SHE). AFs offer the advantage of no stray field, robustness against external field, THz response, and abundance of material

Strongly coupled CdS/graphene quantum dots nanohybrids for highly efficient photocatalytic hydrogen evolution: unraveling the essential roles of graphene quantum dots, Applied Catalysis B,

No abstract

Understanding of the electrical conduction, that is, ionic and electronic conduction, through the solid electrolyte interphase (SEI) is critical to the design of durable lithium-ion batteries (LIBs) with high rate capability and long life. It is believed that an ideal SEI should not only be an ionic conductor, but also an electronic insulator. In this study, we present a theoretical design of an artificial SEI consisting of lithium fluoride (LiF) and lithium carbonate (Li2CO3) on a LIB anode based on a newly developed density functional theory (DFT) informed space charge model. We demonstrate that the migration of lattice Li ions from LiF phase to form Li interstitials in Li2CO3 is energetically favorable near the LiF/Li2CO3 interface. At equilibrium, this interfacial defect reaction establishes a space charge potential across the interface, which causes the accumulation of ionic carriers but the depletion of electronic carriers near the LiF/Li2CO3 interface. To utilize this space charge effect, we propose a computationally designed, nanostructured artificial SEI structure with high density of interfaces of LiF and Li2CO3 perpendicular to the electrode. On the basis of this structure, the influences of grain size and volume ratio of the two phases were studied. Our results reveal that reducing the grain size of Li2CO3 in the nanostructured composite can promote ionic carriers and increase the ionic conductivity through the composite SEI by orders of magnitude. At the same time, the electronic conductivity is reduced due to electron depletion near the LiF/Li2CO3 interface. Furthermore, an optimal volume fraction that ensures high ionic and low electronic conduction was predicted.