Two-dimensional arrays of ferroelectric lead zirconate titanate (PZT) nanodots were fabricated using pulsed laser deposition through ultrathin anodic aluminum oxide membrane stencil masks. The static distribution of polarization configurations was investigated using in- and out-of-plane piezoresponse force microscopy (PFM). The observed presence of an in-plane polarization component in nominally (001) oriented PZT suggests the existence of a significant deviation from the regular tetragonal structure that allows the formation of complex core-polarization states. Core-polarization states may indicate the presence of quasi-toroidal polarization ordering. The experimental results are compared with a theoretical model to determine the fingerprint of a vortex polarization state in PFM.
A high-quality polycrystalline SnO 2 electron-transfer layer is synthesized through an in situ, low-temperature, and unique butanol-water solventassisted process. By choosing a mixture of butanol and water as a solvent, the crystallinity is enhanced and the crystallization temperature is lowered to 130 °C, making the process fully compatible with flexible plastic substrates. The best solar cells fabricated using these layers achieve an efficiency of 20.52% (average 19.02%) which is among the best in the class of planar n-ip-type perovskite (MAPbI 3 ) solar cells. The strongly reduced crystallization temperature of the materials allows their use on a flexible substrate, with a resulting device efficiency of 18%.
Triple cation perovskites (Cs 0.05 (MA 0.17 FA 0.83 ) 0.95 Pb(I 0.83 Br 0.17 ) 3 ) have received lots of attention owing to the excellent stability and photovoltaic performance. However, the development toward efficient solar cells has been significantly impeded by its intrinsic precursor instability, as well as defective crystal surface. Herein, a strategy for introducing the additive of 1,4,7,10,13,16-hexaoxacyclooctadecane (18C6) in the precursor solution, rendering an excellent stability of more than one month, and the defect passivation effect on the crystal surface are demonstrated. In those perovskite solar cells, a power conversion efficiency of 20.73% has been achieved with a substantially improved open-circuit voltage and fill factor. As evidenced by the density functional theory calculations, the fundamental reason relating to the enhanced performance is found to be the interaction effect between the 18C6 and cations, and in particular the formation of the 18C6/Pb complex. This finding represents an alternative strategy for achieving a stable precursor solution and efficient perovskite solar cells.
A novel nanopatterning method using pulsed laser deposition through an ultrathin anodic aluminium oxide (AAO) membrane mask is proposed to synthesize well‐ordered nanodot arrays of magnetic CoFe2O4 that feature a wide range of applications like sensors, drug delivery, and data storage. This technique allows the adjustment of the array dimension from ∼35 to ∼300 nm in diameter and ∼65 to ∼500 nm in inter‐dot distance. The dot density can be as high as 0.21 Terabit in.−2. The microstructure of the nanodots is characterized by SEM, TEM, and XRD and their magnetic properties are confirmed by well‐defined magnetic force microscopy contrasts and by hysteresis loops recorded by a superconducting quantum interference device. Moreover, the high stability of the AAO mask enables the epitaxial growth of nanodots at a temperature as high as 550 °C. The epitaxial dots demonstrate unique complex magnetic domains such as bubble and stripe domains, which are switchable by external magnetic fields. This patterning method creates opportunities for studying novel physics in oxide nanomagnets and may find applications in spintronic devices.
The study of skyrmion/antiskyrmion motion in magnetic materials is very important in particular for the spintronics applications. In this work, we study the dynamics of isolated skyrmions and antiskyrmions in frustrated magnets driven by magnetic field gradient, using the Landau-Lifshitz-Gilbert simulations on the frustrated classical Heisenberg model on the triangular lattice. A Hall-like motion induced by the gradient is revealed in bulk system, similar to that in the well-studied chiral magnets. More interestingly, our work suggests that the lateral confinement in nanostripes of the frustrated system can completely suppress the Hall motion and significantly speed up the motion along the gradient direction. The simulated results are well explained by Thiele theory. It is demonstrated that the acceleration of the motion is mainly determined by the Gilbert damping constant, which provides useful information for finding potential materials for skyrmion-based spintronics.
Perovskite solar cells based on dopant-free PBDT[2F]T have achieved a power conversion efficiency (17.52%), combined with an impressive stability in contrast to that with the doped spiro-OMeTAD as a HTM in ambient atmosphere and even in high humidity.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.