No abstract

Sewage sludge is an important source of introducing microplastics into the environment, and thus, effective mitigation of microplastics in the sludge is in urgent need. Herein, the effect of pyrolysis on microplastics reduction in sewage sludge was investigated through a lab-scale study. The micro-Raman analysis showed that the microplastics concentrations in sludge residues decreased significantly from 550.8 to 960.9 particles/g to 1.4–2.3 particles/g with the pyrolysis temperature increasing to 500 °C, and no tiny (10–50 μm) microplastics remained. Polyethylene and polypropylene, the two most abundant microplastics in sewage sludge, were entirely degraded when the pyrolysis temperature reached 450 °C. However, during the pyrolysis process, new plastic polymers could be produced through the reaction between original microplastics with organics in sludge, and heavy metals in sludge can also be combined. Moreover, scanning electron microscopy analysis of spiked microplastics showed that incomplete pyrolysis at low temperatures could result in rough surface morphology of microplastics, making it more readily to adsorb contaminants. Overall, the results of this study provide the first insight into the effectiveness of microplastics control in sewage sludge through pyrolysis, but to avoid potential environmental risks induced by incomplete pyrolysis, a pyrolysis temperature of 450 °C should be reached at least.

Aerobic digestion followed by dewatering is a widely applied method for sludge stabilization and reduction in decentralized wastewater treatment plants. It is important to enhance the sludge dewaterability of the aerobically digested sludge due to its considerable impact on cost of sludge disposal and management. In this study, an innovative technique is developed for improving the dewaterability of aerobically digested sludge by combined conditioning with persulfate (PS) and zero valent iron (ZVI). The results demonstrated that the dewaterability of aerobically digested sludge could be significantly enhanced with the PS and ZVI dosage in the range of 0 to 0.5 g/gTS and 0 to 0.4 g/gTS, respectively. The highest improvement was achieved at 0.05 g ZVI/g TS with 0.1 g PS/g TS, and the capillary suction time was reduced by ~80%.The extracellular polymeric substances (EPS) characterization revealed that the combined PS-ZVI treatment could largely reduce proteins, polysaccharides and humic acids-like compounds in the tightly bounded EPS of the aerobically digested sludge, leading to bound water releasing from sludge flocs. The recovery of the ZVI particles could reach around 45% -80% after the treatment, further proved the sustainability of the approach. The proposed PS-ZVI conditioning would not have significant impact on the final choice of sludge disposal and the mainstream wastewater treatment. However, plant-scale test are still required for better assessing the proposed technique.

No abstract

No abstract

The chemical characteristics of the refractory organic matter in anaerobic and aerobic digestates are hardly known although they are significant for further improving the degradation of organic matter during sludge digestion.

No abstract