Sewage
sludge is an important source of introducing microplastics
into the environment, and thus, effective mitigation of microplastics
in the sludge is in urgent need. Herein, the effect of pyrolysis on
microplastics reduction in sewage sludge was investigated through
a lab-scale study. The micro-Raman analysis showed that the microplastics
concentrations in sludge residues decreased significantly from 550.8
to 960.9 particles/g to 1.4–2.3 particles/g with the pyrolysis
temperature increasing to 500 °C, and no tiny (10–50 μm)
microplastics remained. Polyethylene and polypropylene, the two most
abundant microplastics in sewage sludge, were entirely degraded when
the pyrolysis temperature reached 450 °C. However, during the
pyrolysis process, new plastic polymers could be produced through
the reaction between original microplastics with organics in sludge,
and heavy metals in sludge can also be combined. Moreover, scanning
electron microscopy analysis of spiked microplastics showed that incomplete
pyrolysis at low temperatures could result in rough surface morphology
of microplastics, making it more readily to adsorb contaminants. Overall,
the results of this study provide the first insight into the effectiveness
of microplastics control in sewage sludge through pyrolysis, but to
avoid potential environmental risks induced by incomplete pyrolysis,
a pyrolysis temperature of 450 °C should be reached at least.
Aerobic digestion followed by dewatering is a widely applied method for sludge stabilization and reduction in decentralized wastewater treatment plants. It is important to enhance the sludge dewaterability of the aerobically digested sludge due to its considerable impact on cost of sludge disposal and management. In this study, an innovative technique is developed for improving the dewaterability of aerobically digested sludge by combined conditioning with persulfate (PS) and zero valent iron (ZVI). The results demonstrated that the dewaterability of aerobically digested sludge could be significantly enhanced with the PS and ZVI dosage in the range of 0 to 0.5 g/gTS and 0 to 0.4 g/gTS, respectively. The highest improvement was achieved at 0.05 g ZVI/g TS with 0.1 g PS/g TS, and the capillary suction time was reduced by ~80%.The extracellular polymeric substances (EPS) characterization revealed that the combined PS-ZVI treatment could largely reduce proteins, polysaccharides and humic acids-like compounds in the tightly bounded EPS of the aerobically digested sludge, leading to bound water releasing from sludge flocs. The recovery of the ZVI particles could reach around 45% -80% after the treatment, further proved the sustainability of the approach. The proposed PS-ZVI conditioning would not have significant impact on the final choice of sludge disposal and the mainstream wastewater treatment. However, plant-scale test are still required for better assessing the proposed technique.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.