A bimetallic-structured ternary phosphide (NiCo P ) as a novel pH-universal electrocatalyst for hydrogen evolution reaction is presented. It exhibits both high activity and long-term stability in all the tested alkaline, neutral, and acidic media. The excellent catalytic performance endows it with a bright future in the large-scale electrochemical water splitting industry.
We fabricated a C fullerene-based molecular spin-photovoltaic device that integrates a photovoltaic response with the spin transport across the molecular layer. The photovoltaic response can be modified under the application of a small magnetic field, with a magnetophotovoltage of up to 5% at room temperature. Device functionalities include a magnetic current inverter and the presence of diverging magnetocurrent at certain illumination levels that could be useful for sensing. Completely spin-polarized currents can be created by balancing the external partially spin-polarized injection with the photogenerated carriers.
The last two years have witnessed the rapid progress of organic solar cells (OSCs), driven by the newly developed nonfullerene acceptor (NFA) Y6, which contains an electron-deficient-core-based central fused ring....
Taking advantage of the "coffee-ring" effect, graphene electrodes with channel lengths as low as 1-2 micrometers are patterned by inkjet printing. Organic thin film transistors and complementary inverters are also fabricated using these graphene electrodes and show excellent performance.
Organic semiconductors, characterized by weak spin-scattering mechanisms, are attractive materials for those spintronic applications in which the spin information needs to be retained for long times. Prototypical spin-valve devices employing organic interlayers sandwiched between ferromagnetic materials possess a figure of merit (magnetoresistance (MR)) comparable to their fully inorganic counterparts. However, these results are a matter of debate as the conductivity of the devices does not show the expected temperature dependence. Here we show spin valves with an interlayer of bathocuproine in which the transport takes place unambiguously through the organic layer and where the electron spin coherence is maintained over large distances (460 nm) at room temperature. Additionally, the devices show excellent air stability, with MR values almost unaltered after 70 days of storage under ambient conditions, making bathocuproine an interesting material for future spintronic applications.
Long distance spin transport and photoresponse are demonstrated in a single F16 CuPc spin valve. By introducing a low-temperature strategy for controlling the morphology of the organic layer during the fabrication of a molecular spin valve, a large spin-diffusion length up to 180 nm is achieved at room temperature. Magnetoresistive and photoresponsive signals are simultaneously observed even in an air atmosphere.
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