Owing to growing environmental concerns, the development of lead-free piezoelectrics with comparable performance to the benchmark Pb(Zr,Ti)O3 (PZT) becomes of great urgency. However, a further enhancement of lead-free piezoelectrics based on existing strategies has reached a bottleneck. Here we achieve a slush polar state with multiphase coexistence in lead-free potassium–sodium niobate (KNN) piezoceramics, which shows a novel relaxor behavior, i.e., frequency dispersion at the transition between different ferroelectric phases. It is very different from the conventional relaxor behavior which occurs at the paraelectric–ferroelectric phase transition. We obtain an ultrahigh piezoelectric coefficient (d 33) of 650 ± 20 pC/N, the largest value of nontextured KNN-based ceramics, outperforming that of the commercialized PZT-5H. Atomic-resolution polarization mapping by Z-contrast imaging from different orientations reveals the entire material to comprise polar nanoregions with multiphase coexistence, which is again very different from conventional ferroelectric relaxors which have polar domains within a nonpolar matrix. Theoretical simulations validate the significantly decreased energy barrier and polarization anisotropy, which is facilitated by the high-density domain boundaries with easy polarization rotation bridging the multiphase-coexisting nanodomains. This work demonstrates a new strategy for designing lead-free piezoelectrics with further enhanced performance, which should also be applicable to other functional materials requiring a slush (flexible) state with respect to external stimulus.
Due to growing environmental concerns on the toxicity of lead-based piezoelectric materials, lead-free alternatives are urgently required but so far have not been able to reach competitive performance. Here we employ a novel phase-boundary engineering strategy utilizing the multiphase convergence, which induces a broad structural flexibility in a wide phase-boundary zone with contiguous polymorphic phase transitions. We achieve an ultrahigh piezoelectric constant (d 33) of 700 ± 30 pC/N in BaTiO3-based ceramics, maintaining >600 pC/N over a wide composition range. Atomic resolution polarization mapping by Z-contrast imaging reveals the coexistence of three ferroelectric phases (T + O + R) at the nanoscale with nanoscale polarization rotation between them. Theoretical simulations confirm greatly reduced energy barriers facilitating polarization rotation. Our lead-free material exceeds the performance of the majority of lead-based systems (including the benchmark PZT-5H) in the temperature range of 10–40 °C, making it suitable as a lead-free replacement in practical applications. This work offers a new paradigm for designing lead-free functional materials with superior electromechanical properties.
Basalt fiber has a great advantage on the mechanical properties and durability of reactive powder concrete (RPC) because of its superior mechanical properties and chemical corrosion resistance. In this paper, basalt fiber was adopted to modified RPC, and plain reactive powder concrete (PRPC), basalt fiber reactive powder concrete (BFRPC) and steel fiber reactive powder concrete (SFRPC) were prepared. The mechanical properties and freeze–thaw durability of BFRPC with different basalt fiber contents were tested and compared with PRPC and SFRPC to investigate the effects of basalt fiber contents and fiber type on the mechanical properties and freeze–thaw durability of RPC. Besides, the mass loss rate and compressive strength loss rate of RPC under two freeze–thaw conditions (fresh-water freeze–thaw and chloride-salt freeze–thaw) were tested to evaluate the effects of freeze–thaw conditions on the freeze–thaw durability of RPC. The experiment results showed that the mechanical properties and freeze–thaw resistance of RPC increased as the basalt fiber content increase. Compared with the fresh-water freeze–thaw cycle, the damage of the chloride-salt freeze–thaw cycle on RPC was great. Based on the freeze–thaw experiment results, it was found that SFRPC was sensitive to the corrosion of chloride salts and compared with the steel fiber, the improvement of basalt fiber on the freeze–thaw resistance of RPC was great.
This paper presented a laboratory investigation for analyzing the natural frequency response of reinforced concrete (RC) beams affected by steel corrosion. The electrochemical acceleration technique induced the corroded RC beams until the predetermined value of the steel corrosion ratio was achieved. Then, the natural frequency responses of the corroded beams were tested utilizing piezoelectric acceleration sensors. The damage states of the corroded beams were assessed through the measurement of crack parameters and the equivalent elastic modulus of the beams, which aims to clarify the fundamental characteristics of the dynamic response for the corroded RC beam with the increased steel corrosion ratio. The results revealed that steel corrosion reduces the bending stiffness of the RC beams and, thus, reduces the modal frequency. The variation of natural frequency can identify the corrosion damage even if no surface cracking of the RC beam, and the second-order frequency should be more indicative of the damage scenario. The degradations of stiffness and the natural frequency were estimated in this study by the free vibration equation of a simply supported beam, and a prediction method for the RC beam’s residual service life was established. This study supports the use of variations in natural frequency as one diagnostic indicator to evaluate the health of RC bridge structures.
The urban environment is facing serious problems caused by automobile exhaust pollution, which has led to a great impact on human health and climate, and aroused widespread concern of the government and the public. Nano titanium dioxide (TiO2), as a photocatalyst, can be activated by ultraviolet irradiation and then form a strong REDOX potential on the surface of the nano TiO2 particles. The REDOX potential can degrade the automobile exhaust, such as nitrogen oxides (NOx) and hydrocarbons (HC). In this paper, a photocatalytic environmentally friendly pervious concrete (PEFPC) was manufactured by spraying nano TiO2 on the surface of it and the photocatalytic performance of PEFPC was researched. The nano TiO2 particle size, TiO2 dosage, TiO2 spraying amount, and dispersant dosage were selected as factors to investigate the efficiency of photocatalytic degradation of automobile exhaust by PEFPC. Moreover, the environmental scanning electron microscope (ESEM) was used to evaluate the distribution of nano TiO2 on the surface of the pervious concrete, the distribution area of nano TiO2 was obtained through Image-Pro Plus, and the area ratio of nano TiO2 to the surface of the pervious concrete was calculated. The results showed that the recommended nano TiO2 particle size is 25 nm. The optimum TiO2 dosage was 10% and the optimum dispersant dosage was 5.0%. The photocatalytic performance of PEFPC was best when the TiO2 spraying amount was 333.3 g/m2. The change in the photocatalytic ratio of HC and NOx is consistent with the distribution area of nano TiO2 on the surface of the pervious concrete. In addition, the photocatalytic performance of PEFPC under two light sources (ultraviolet light and sunlight) was compared. The results indicated that both light sources were able to stimulate the photocatalytic performance of PEFPC. The research provided a reference for the evaluation of automobile exhaust removal performance of PEFPC.
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