The use of chemically selective laser ionization combined with b-delayed neutron counting at CERN/ISOLDE has permitted identification and half-life measurements for 623-ms 61 Mn up through 14-ms 69 Mn. The measured half-lives are found to be significantly longer near N 40 than the values calculated with a quasiparticle random-phase-approximation shell model. Gamma-ray singles and coincidence spectroscopy has been performed for 64,66 In addition to the clear nuclear-structure interest, the neutron-rich Fe-group nuclei may also play an important role as possible seed nuclei in the astrophysical r process [13]. In the present paper, we report new measurements for the half-lives of heavy Mn nuclides up to 69 Mn and for the level structure of 64,66 Fe populated in the decays of 64,66 Mn.Manganese isotopes were produced at CERN by 1-GeV proton-induced spallation of uranium in a thick UC 2 target at the ISOLDE facility. The ionization of the Mn atoms was accomplished using a chemically selective, three-step laser resonance excitation scheme as described in detail earlier [14].Beams of Mn nuclides with masses differing by DA $ 4 were transported separately to two different beam lines equipped with moving tape systems where b-delayed neutron (d.n.) multiscaling and g-ray singles and coincidence measurements could be performed independently. In both cases, counting took place directly at the point of deposit, and the tape systems were used to remove the daughter nuclides as well as unavoidable surfaceionized isobaric Ga activities. Because the Mn half-lives being sought are in the millisecond range, data acquisition in both systems was initiated by the proton pulses from the CERN proton-synchrotron booster (PSB), separated by a multiple of 1.2 s, and continued for 1.0 s for each cycle.Beta-delayed neutron data of high statistical quality were collected by multiscaling measurements using the Mainz 4p 3 He neutron counter. The time dependence of the counting rates for 65 69 Mn is shown in Fig. 1. The decay curves were fitted with a constant small d.n.-background component up through A 65. Because there exist no measured d.n.-emission probabilities (P n values) for the A . 65 daughter and granddaughter isobars, the fits of the heavier isotopes were performed using theoretical P n values [10] along with the known half-lives [5,7,8,15]. For A 66 68, the contributions from d.n. emission of the Fe and Co isobars are quite small and actually do not affect the Mn half-life fits. For A 69, however, a multicomponent fit was necessary to account for the significant Fe and Co d.n. branches. The resulting data are summarized in Table I 0031-9007͞99͞82(7)͞1391(4)$15.00

Several new progressions consisting of broadbands have been observed in the absorption spectra of NO trapped in rare gas matrices. They are identified as the blue shifted transitions to the n=3 (A 2Σ+,C 2Π,D 2Σ+) and n=4 (E 2Σ+,K 2Π,M 2Σ+) Rydberg states of NO in Ne matrices and to the n=3 Rydberg states in Ar, Kr, and Xe matrices. Linewidths (50 to 180 meV) and matrix shifts (0.3 to 1.2 eV) decrease from neon to xenon matrices. For each matrix, the shifts decrease according to the symmetry of the excited state orbital, in the sequence sσ–pσ–pπ. An attempt to apply the quantum defect formula with values, for the Rydberg constant and the ionization potential of the matrix isolated molecule taken from literature, fails to describe the vertical transition energies of n=3 and n=4 states in neon matrices. On the other hand, using the adiabatic energies of 3sσ and 4sσ states to generate a series shows that the vertical transitions of n≥5 states lie in the ionization continuum. This could explain the nonobservation of n>4 states in Ne matrices. In the heavier matrices, this model predicts n=4 states but their existence is not borne out by experiment. The Wannier model also fails to describe these transitions.

The polycyclic musk compounds HHCB (Galaxolide) and AHTN (Tonalide) are commonly used as synthetic fragrances in personal care products and household cleaners. These and other synthetic musk fragrances were quantified in different aquatic samples from the German Environmental Specimen Bank (ESB). While HHCB and AHTN were found in almost all samples, most of the other musk fragrances were detected only in a few samples and mostly at lower concentration levels. Blue mussels from the North Sea showed varying levels of 0.5-1.7 ng g(-1) ww for HHCB and 0.4-2.5 ng g(-1) ww for AHTN (ww, wet weight) in the period from 1986 to 2000, while blue mussels from the Baltic Sea were only slightly contaminated with synthetic musk fragrances. Lipid weight-related concentrations of synthetic musk compounds in blue mussels were higher than in eelpout muscles, bladder wrack and herring gull eggs. In comparison to the marine specimens, muscles of bream from German rivers had higher concentrations of HHCB and AHTN. The ranges of HHCB and AHTN concentrations in bream from the Elbe River were 545-6400 ng g(-1) lw and 48-2130 ng g(-1) lw, respectively (lw, lipid weight; five sampling sites, period 1993-2003). In the Rhine River, HHCB and AHTN levels of bream muscles were highest at the Iffezheim site (up to 9750 ng g(-1) lw HHCB, 1998). Even higher synthetic musk levels were detected in bream from the rivers Saale and Saar. In recent years, levels of both compounds determined in bream from most sampling sites have decreased from maximum values in the 1990s. As the concentrations of AHTN have decreased faster, the ratio of HHCB to AHTN increased from 2-4 in the 1990s to 10-20 in recent years.

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Breams (Abramis brama) and zebra mussels (Dreissena polymorpha) from freshwater, and common mussels (Mytilus edulis) from marine ecosystems, archived in the German Environmental Specimen Bankwere analyzed for the presence of 4-nonylphenol (NP), 4-tert-octylphenol (OP), nonylphenol monoethoxylate (NP1EO), and octylphenol monoethoxylate (OP1EO). The samples were collected in the German rivers Elbe, Rhine, and Saar, and in Lake Belau between 1992 and 2001, as well as in the North Sea and Baltic Sea between 1985 and 2001. The main purpose of the study was to investigate the effectiveness of imposed reduction measures regarding the use of alkylphenol ethoxylates. NP1EO and OP were detected in all breams. NP was predominantly above the limit of quantification (LOQ, 2 ng/g; all data on a wet weight basis), and OP1EO was mostly below the LOQ (0.2 ng/g). Maximal concentrations of 112 ng/g NP, 259 ng/g NP1EO, 5.5 ng/g OP, and 2.6 ng/g OP1EO were found in Saar breams from 1994. NP was detected in all zebra mussels from the river Elbe (up to 41 ng/g), whereas in rather few samples OP and NP1EO were found at low levels. OP1EO was not detected in any sample. Concentrations in mussels and breams from the reference site Lake Belau were below the LOQ for all compounds. In marine biota NP was found until 1997 with maximum concentrations up to 9.7 ng/g, whereas NP1EO was detected at levels between 1.7 and 12.9 ng/g in very few samples collected at the end of the 1980s. A tendency of the concentrations to decrease was obvious for all sampling sites; it was most pronounced for NP1EO and NP after 1996/1997. The effectiveness of the reduction measures is most evident at the Saar sampling site Güdingen and the North Sea sampling site Eckwarderhörne.

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An investigation of the dependence on temperature of the extended X-ray absorption fine structure (EXAFS) above the K-edges of Cu and Co in the metals and above the K-edges of Rb and Sr in the compounds RbCl, SrS, SrF2 and SrCl2 has been performed. For Cu, Co, RbCl and SrS, the values of the correlated mean square relative displacements of nearest-neighbour atoms derived from EXAFS spectra show a good agreement with those calculated from a Debye model. The experimental data obtained are also compared with available data for mean square displacements of the individual atoms calculated from more-refined lattice vibrational models and with Debye-Waller factors used in X-ray diffraction experiments.