This paper presents the rheological properties of three types of lime putty, specifying the influence of their origin. The study aims to compare a special lime putty prepared from phosphogypsum with a commercial lime powder and an aged lime putty. The results obtained in terms of chemical composition, crystalline structure, grain size and rheological characterization, (linear viscoelasticity, shear rate and time-dependent flow behaviour) are presented in the study. Putties studied present a similar rheological response, which mainly depends on the particle size and water content. Lower values of the linear viscoelastic functions and viscosity were found for the phosphogypsum lime putty, in agreement with the higher particle size. Transient flow tests reveal a predominant elastic response with no significant shear-induced structural perturbations. However, either a thickening phenomenon over time, i.e. rheopexy, favoured at
The aim of the present work was to characterize the products obtained from the treatment of phosphogypsum residue by means of two recovery routes, and also to evaluate the concentrations of heavy metals and radionuclides in the materials obtained and their leachates. In this way, it is possible to determine how the most hazardous components of phosphogypsum behave during procedures until their stabilization through CO2 fixation. This study provides an initial estimate of the possibilities of reusing the resulting products from a health and safety risk standpoint and their potential polluting capacity. The phases resulting from the transformations were controlled, and the behaviour of standard mortars manufactured from the resulting paste lime was studied. In all cases, an additional control of the leachate products was performed.
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