The main compounds of plant biomass, i.e., cellulose, lignin and hemicellulose, were submitted to hydrothermal carbonisation (HTC) in ranges of temperature and time of 140-240ºC and 0.5-24 h, respectively. Those parameters were combined into a single one, the severity factor, and its effect on hydrochar yield on the one hand, and on pH, yield and composition of the liquid fraction on the other hand, was investigated in depth. The production of furanic and phenolic compounds was correlated with both severity and pH. The kinetics of furfural (FU) and 5-hydroxymethylfurfural (5-HMF) production and consumption were also investigated and modelled, and the results were compared to those reported in the literature. The production of nine phenolic compounds from lignin HTC was also considered.
This work describes the solid-state fermentation (SSF) of wheat straw with Streptomyces sp. MDG147 and further soda-pulping process to obtain wheat straw soda lignins (WSLs). Subsequently, these WSLs were NCO-functionalized with 1,6-hexamethylene diisocyanate and then dispersed in castor oil to achieve stable oleogels. The WSLs were characterized using standard analytical methods, gel permeation chromatography, Fourier transform infrared spectroscopy, differential scanning calorimetry, and thermogravimetric analysis. Rheological properties of oleogels were determined by means of small-amplitude oscillatory shear and viscous flow measurements. The enzymatic profile and production of lignin−carbohydrate complexes were recorded along the growth time of Streptomyces, whose life cycle was achieved after 7 days. NCO-functionalized WSL was able to chemically interact with castor oil via urethane bonding, providing oleogels with suitable rheological characteristics. Linear viscoelastic functions and viscosity values of oleogels were higher when wheat straw was submitted to SSF using Streptomyces, turning out in stronger oleogels.
In this work, alkali lignin together with different diisocyanates (hexamethylene diisocyanate (HDI), isophorone diisocyanate (IDI), toluene diisocyanate (TDI) and 4,4′methylenebis (phenyl isocyanate) (MDI)) have been tested as gelling agents in a castor oil medium. A two-step process comprising first lignin functionalization with a diisocyanate and then the formation of a bio-based polyurethane with gel-like characteristics by combining the functionalized lignin with castor was followed. FTIR and thermogravimetry analysis were carried out on both the gelling agents and resulting oleogels. Moreover, oleogel rheological properties were evaluated by means of smallamplitude oscillatory shear (SAOS) tests and viscous flow measurements. The influences of time-temperature processing conditions during oleogel formation, lignin/diisocyanate ratio and functionalized lignin concentration on the rheological properties of oleogels were analyzed using HDI as crosslinker. 30% (w/w) thickener concentration and room temperature processing were selected to prepare oleogels with the rest of diisocyanates considered. Under the same conditions, HDI-functionalized lignin-based oleogels showed the strongest gel-like behavior whereas TDI-, IDI-and especially MDI-functionalized lignin-based oleogels displayed weak gel-like, or even a liquid-like, behaviors as a consequence of the respective chemical structures, which guide to higher steric hindrance, diminishing the formation of urethane linkages and/or Van der Waals forces. In general, oleogels exhibited an internal curing process due to the progressive formation of urethane linkages, which is closely related to the evolving rheological properties. The kinetics of this curing process was studied and an empirical model has been proposed to predict the evolution of the rheological properties with time.
Olive stones (OS) were submitted to hydrothermal carbonisation (HTC) in order to evaluate the possibility of producing high added-value products, mainly furfural (FU) and 5-hydroxymethylfurfural (5-HMF) on one hand and hydrochars and carbons on the other hand. Temperature (160-240 °C), residence time (1-8 h), initial pH (1-5.5) and liquid/solid ratio (4-48 w/w) were systematically varied in order to study the main products and to optimise FU production. FU production yield up to 19.9 %, based on the hemicellulose content, was obtained. Other minor, but valuable, compounds such as 5-methylfurfural (5-MF) and some phenolic compounds were also produced. The hydrochar was carbonised at 900 °C, and the resultant carbon material was highly ultramicroporous with a peak of pore size distribution centred on 0.5 nm and a surface area as high as 1065 m g, typical of most carbon molecular sieves.
This paper presents the rheological properties of three types of lime putty, specifying the influence of their origin. The study aims to compare a special lime putty prepared from phosphogypsum with a commercial lime powder and an aged lime putty. The results obtained in terms of chemical composition, crystalline structure, grain size and rheological characterization, (linear viscoelasticity, shear rate and time-dependent flow behaviour) are presented in the study. Putties studied present a similar rheological response, which mainly depends on the particle size and water content. Lower values of the linear viscoelastic functions and viscosity were found for the phosphogypsum lime putty, in agreement with the higher particle size. Transient flow tests reveal a predominant elastic response with no significant shear-induced structural perturbations. However, either a thickening phenomenon over time, i.e. rheopexy, favoured at
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