Development of next-generation sensor devices is gaining tremendous attention in both academia and industry because of their broad applications in manufacturing processes, food and environment control, medicine, disease diagnostics, security and defense, aerospace, and so forth. Current challenges include the development of low-cost, ultrahigh, and user-friendly sensors, which have high selectivity, fast response and recovery times, and small dimensions. The critical demands of these new sensors are typically associated with advanced nanoscale sensing materials. Among them, graphene and its derivatives have demonstrated the ideal properties to overcome these challenges and have merged as one of the most popular sensing platforms for diverse applications. A broad range of graphene assemblies with different architectures, morphologies, and scales (from nano-, micro-, to macrosize) have been explored in recent years for designing new high-performing sensing devices. Herein, this study presents and discusses recent advances in synthesis strategies of assembled graphene-based superstructures of 1D, 2D, and 3D macroscopic shapes in the forms of fibers, thin films, and foams/aerogels. The fabricated state-of-the-art applications of these materials in gas and vapor, biomedical, piezoresistive strain and pressure, heavy metal ion, and temperature sensors are also systematically reviewed and discussed, and their sensing performance is compared.
MXenes, a new family of two-dimensional transition metal carbides/nitrides, have been exploited in 3D bioprinting owing to their outstanding properties such as a large specific surface area, high electrical conductivity, and biodegradability.
Graphene and related 2D materials offer an ideal platform for next generation disruptive technologies and in particular the potential to produce printed electronic devices with low cost and high throughput....
Here, we report a new method to prepare graphene from graphite by the liquid phase exfoliation process with sonication using graphene oxide (GO) as a dispersant. It was found that GO nanosheets act a as surfactant to the mediated exfoliation of graphite into a GO-adsorbed graphene complex in the aqueous solution, from which graphene was separated by an additional process. The preparation of isolated graphene from a single to a few layers is routinely achieved with an exfoliation yield of up to higher than 40% from the initial graphite material. The prepared graphene sheets showed a high quality (C/O ∼ 21.5), low defect (ID/IG ∼ 0.12), and high conductivity (6.2 × 10(4) S/m). Moreover, the large lateral size ranging from 5 to 10 μm of graphene, which is believed to be due to the shielding effect of GO avoiding damage under ultrasonic jets and cavitation formed by the sonication process. The thin graphene film prepared by the spray-coating technique showed a sheet resistance of 668 Ω/sq with a transmittance of 80% at 550 nm after annealing at 350 °C for 3 h. The transparent electrode was even greater with the resistance only 66.02 Ω when graphene is deposited on an interdigitated electrode (1 mm gap). Finally, a flexible sensor based on a graphene spray-coating polydimethylsiloxane (PDMS) is demonstrated showing excellent performance working under human touch pressure (<10 kPa). The graphene prepared by this method has some distinct properties showing it as a promising material for applications in electronics including thin film coatings, transparent electrodes, wearable electronics, human monitoring sensors, and RFID tags.
The membrane phospholipid phosphatidylserine is exposed on the cell surface during apoptosis and acts as an eat-me signal in the phagocytosis of apoptotic cells in mammals and nematodes. However, whether this is also true in insects was unclear. When milk fat globule-epidermal growth factor 8, a phosphatidylserine-binding protein of mammals, was ectopically expressed in Drosophila, the level of phagocytosis was reduced, whereas this was not the case for the same protein lacking a domain responsible for the binding to phosphatidylserine. We found that the extracellular region of Draper, an engulfment receptor of Drosophila, binds to phosphatidylserine in an enzyme-linked immunosorbent assay-like solid-phase assay and in an assay for surface plasmon resonance. A portion of Draper containing domains EMI and NIM located close to the N-terminus was required for binding to phosphatidylserine, and a Draper protein lacking this region was not active in Drosophila. Finally, the level of tyrosine-phosphorylated Draper, indicative of the activation of Draper, in a hemocyte-derived cell line was increased after treatment with phosphatidylserine-containing liposome. These results indicated that phosphatidylserine serves as an eat-me signal in the phagocytic removal of apoptotic cells in Drosophila and that Draper is a phosphatidylserine-binding receptor for phagocytosis.
To resist the energy crisis and increasingly environmental pollution, there is a great demand for the development of sustainable materials for use in high-performance energy storage devices and environmental applications. However, it is a great challenge to realize both ultrahigh power density and high energy density in symmetric supercapacitors (SCs) by using materials synthesized from bioresources. Herein, we report the synthesis of hierarchical and lightweight graphene aerogels (GAs) with interconnected three-dimensional (3D) nanostructures for the fabrication of high performance coin cell-type SCs. GAs synthesized from pear exhibited high surface area (1001 m 2 g −1 ) and pore volume (0.68 cm 3 g −1 ), which tremendously increase its surface area up to 2323 m 2 g −1 and pore volume of 1.15 cm 3 g −1 after chemical activation. SCs based on activated GAs delivered both high energy density of 56.80 Wh kg −1 and high power density of 620.26 kW kg −1 . The capacitance retention was ∼83% after 10 000 successive cycles of charge/discharge, indicating good cyclability. Moreover, GAs showed great potential as excellent adsorbents for the removal of diverse dyes from wastewater. This approach allows us to take the full advantage of raw materials from nature for promising applications in sustainable energy as high-performance SCs and practical environmental remediation.
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