Microperoxidase-11(MP-11) has been immobilized for the first time in hybrid periodic mesoporous organosilica (PMO) materials and in a nano-crystalline metal organic framework (MOF). Microperoxidase-11 was physically absorbed from solution into the periodic mesoporous organosilica MBS and functionalized derivatives of MBS as well as in the 3-dimensional [Cu(OOC-C 6 H 4 -C 6 H 4 -COO)AE½ C 6 H 12 N 2 ] n metal organic framework. The conversion of Amplex Ò UltraRed and methylene blue to their respective oxidation products by immobilized MP-11 was determined.

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