Preparation and characterization of UTD-12/ZSM-48 thin films via pulsed-laser deposition

Encapsulation of cobaltocenium ions in a zeolite-like metal–organic framework

“…1 (Cp 2 Co + , Cp = C 5 H 5 ) has been shown to be a structure directing agent (SDA) for several zeolites, 40 including the 10-membered ring UTD-12 zeolite. 41 In comparison, the larger pentamethyl cobaltocenium ion makes the 14-membered ring zeolite, UTD-1. 42 Zeolite-like metal-organic frameworks (ZMOFs) comprise a subclass of MOFs.…”

Fabrication of Oriented Silver-Functionalized RPM3 Films for the Selective Detection of Olefins

“…Another method known as pulsed laser deposition (PLD) is an interesting seeding approach because it directly “anchors” the porous material to the substrate of choice. The PLD method has been used to prepare oriented thin films of molecular sieves including UTD-1, AlPO 4 -5, FeAPO-5, MCM-41, MCM-22, NaX, , UTD-12, ZSM-5, and ZSM-48 . PLD produces high energy atoms, ions, and molecules that are deposited on a substrate, which are then hydrothermally treated to form a crystalline film.…”

“…PLD produces high energy atoms, ions, and molecules that are deposited on a substrate, which are then hydrothermally treated to form a crystalline film. This method has several advantages such as controllable film thickness, good adhesion properties, and in some cases formation of oriented thin films . We have previously employed the PLD method to fabricate thin films and membranes of ZIF-8 on various glass substrates for water/ethanol separation…”

“…This method has several advantages such as controllable film thickness, good adhesion properties, and in some cases formation of oriented thin films. 39 We have previously employed the PLD method to fabricate thin films and membranes of ZIF-8 on various glass substrates for water/ethanol separation. 41 In the present study, RPM3 (Rutger's Recyclable Porous Material-3 or (Zn 2 (bpdc) 2 (bpee)) was prepared as an oriented thin film via PLD.…”

Laser Control of Zeolite Nucleation

“…Lasers are currently used for the synthesis of a number of inorganic nanoparticles10, 11 and even for the characterization of zeolites,9, 12, 13 although their application in the modification of previously synthesized zeolites has been scarce. Seeding through pulsed laser ablation has made possible the preparation of oriented zeolite UTD‐1,14 zeolite X,15 mordenite,16 and UTD‐2/ZSM‐4817 zeolite membranes, while zeolite LTA nanoparticles have been obtained in the liquid phase by laser‐induced fracture of zeolite microcrystals 18. Recently, zeolite L was doped with Au through a simultaneous laser ablation and a crystallization inclusion procedure carried out also in solution 19.…”