Hybrid materials for immobilization of MP-11 catalyst

Pisklak, Thomas J.; Macías, Minedys; Coutinho, Decio; Huang, Rita; Balkus, Kenneth J.

doi:10.1007/s11244-006-0025-6

Cited by 114 publications

(61 citation statements)

References 70 publications

(43 reference statements)

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“…The authors also prepared horseradish peroxidase/ZIF‐8, lipase/ZIF‐8, and Cyt c/ZIF‐10 nanocomposites using the same method. This entrapment method is distinct from other works that immobilized small proteins/enzymes with MOFs …”

Section: Nmofs For Therapeutic Applicationsmentioning

confidence: 96%

Nanoscale Metal–Organic Frameworks for Therapeutic, Imaging, and Sensing Applications

et al. 2018

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Nanotechnology has played an important role in drug delivery and biomedical imaging over the past two decades. In particular, nanoscale metal-organic frameworks (nMOFs) are emerging as an important class of biomedically relevant nanomaterials due to their high porosity, multifunctionality, and biocompatibility. The high porosity of nMOFs allows for the encapsulation of exceptionally high payloads of therapeutic and/or imaging cargoes while the building blocks-both ligands and the secondary building units (SBUs)-can be utilized to load drugs and/or imaging agents via covalent attachment. The ligands and SBUs of nMOFs can also be functionalized for surface passivation or active targeting at overexpressed biomarkers. The metal ions or metal clusters on nMOFs also render them viable candidates as contrast agents for magnetic resonance imaging, computed tomography, or other imaging modalities. This review article summarizes recent progress on nMOF designs and their exploration in biomedical areas. First, the therapeutic applications of nMOFs, based on four distinct drug loading strategies, are discussed, followed by a summary of nMOF designs for imaging and biosensing. The review is concluded by exploring the fundamental challenges facing nMOF-based therapeutic, imaging, and biosensing agents. This review hopefully can stimulate interdisciplinary research at the intersection of MOFs and biomedicine.

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Section: Nmofs For Therapeutic Applicationsmentioning

confidence: 96%

Nanoscale Metal–Organic Frameworks for Therapeutic, Imaging, and Sensing Applications

et al. 2018

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“…A widely used technique for enzyme protection is by inserting the enzymes in the presynthesized MOF particles through pore insertion (67). The postinfiltration method is sufficiently reported to accommodate various biomacromolecules with different sizes in a range of MOFs (20,68,69). One substantial drawback of this approach is that biomolecules significantly larger than the pore size of the host could not be encapsulated.…”

Section: Exogenous Bioaugmentationmentioning

confidence: 99%

Nanobiohybrids: Materials approaches for bioaugmentation

et al. 2020

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Nanobiohybrids, synthesized by integrating functional nanomaterials with living systems, have emerged as an exciting branch of research at the interface of materials engineering and biological science. Nanobiohybrids use synthetic nanomaterials to impart organisms with emergent properties outside their scope of evolution. Consequently, they endow new or augmented properties that are either innate or exogenous, such as enhanced tolerance against stress, programmed metabolism and proliferation, artificial photosynthesis, or conductivity. Advances in new materials design and processing technologies made it possible to tailor the physicochemical properties of the nanomaterials coupled with the biological systems. To date, many different types of nanomaterials have been integrated with various biological systems from simple biomolecules to complex multicellular organisms. Here, we provide a critical overview of recent developments of nanobiohybrids that enable new or augmented biological functions that show promise in high-tech applications across many disciplines, including energy harvesting, biocatalysis, biosensing, medicine, and robotics.

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“…MP 11 was immobilized in hybrid periodic mesoporous organosilica materials and in a nano-crystalline metal organic [Cu(OOC-C6H4-C6H4-COO)AE C6H12N2] n framework. The conversion of Amplex-Ultra Red and Methylene Blue to their respective oxidation products catalyzed successfully in the presence of immobilized MP 11 (Pisklak et al 2006).…”

Section: Microperoxidase 11mentioning

confidence: 99%

Peroxidase mediated decolorization and remediation of wastewater containing industrial dyes: a review

Husain

2009

Rev Environ Sci Biotechnol

209

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In this article an effort has been made to review literature based on the role of peroxidases in the treatment and decolorization of a wide spectrum aromatic dyes from polluted water. Peroxidases can catalyze degradation/transformation of aromatic dyes either by precipitation or by opening the aromatic ring structure. Peroxidases from plant sources; horseradish, turnip, tomato, soybean, bitter gourd, white radish and Saccharum uvarum and microbial sources; lignin peroxidases, manganese peroxidases, vanadium haloperoxidases, versatile peroxidases, dye decolorizing peroxidases have been employed for the remediation of commercial dyes. Soluble and immobilized peroxidases have been successfully exploited in batch as well as in continuous processes for the treatment of synthetic dyes with complex aromatic molecular structures present in industrial effluents at large scale. However, recalcitrant dyes were also decolorized by the action of peroxidases in the presence of redox mediators.

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Hybrid materials for immobilization of MP-11 catalyst

Cited by 114 publications

References 70 publications

Nanoscale Metal–Organic Frameworks for Therapeutic, Imaging, and Sensing Applications

Nanoscale Metal–Organic Frameworks for Therapeutic, Imaging, and Sensing Applications

Nanobiohybrids: Materials approaches for bioaugmentation

Peroxidase mediated decolorization and remediation of wastewater containing industrial dyes: a review

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