Semi-transparent perovskite solar cells are highly attractive for a wide range of applications, such as bifacial and tandem solar cells; however, the power conversion efficiency of semi-transparent devices still lags behind due to missing suitable transparent rear electrode or deposition process. Here we report a low-temperature process for efficient semi-transparent planar perovskite solar cells. A hybrid thermal evaporation–spin coating technique is developed to allow the introduction of PCBM in regular device configuration, which facilitates the growth of high-quality absorber, resulting in hysteresis-free devices. We employ high-mobility hydrogenated indium oxide as transparent rear electrode by room-temperature radio-frequency magnetron sputtering, yielding a semi-transparent solar cell with steady-state efficiency of 14.2% along with 72% average transmittance in the near-infrared region. With such semi-transparent devices, we show a substantial power enhancement when operating as bifacial solar cell, and in combination with low-bandgap copper indium gallium diselenide we further demonstrate 20.5% efficiency in four-terminal tandem configuration.
We report on the generation of radially and azimuthally polarized Q-switched laser radiation and its application in material processing. The power levels were sufficiently high to study micro-hole drilling in different metals. Depending on the optical properties of the metal, either radial or azimuthal polarization shows the best efficiency and the effect is attributed to waveguiding. For steel, a comparison to linearly or circularly polarized laser radiation indicates that the doughnut-shaped beam with azimuthal polarization is the most energy-efficient in producing holes of the same diameter and depth.
This review summarizes the current status of Cu(In,Ga)(S,Se) 2 (CIGS) thin film solar cell technology with a focus on recent advancements and emerging concepts intended for higher efficiency and novel applications. The recent developments and trends of research in laboratories and industrial achievements communicated within the last years are reviewed, and the major developments linked to alkali post deposition treatment and composition grading in CIGS, surface passivation, buffer, and transparent contact layers are emphasized. Encouraging results have been achieved for CIGS-based tandem solar cells and for improvement in low light device performance. Challenges of technology transfer of lab's record high efficiency cells to average industrial production are obvious from the reported efficiency values. One section is dedicated to development and opportunities offered by flexible and lightweight CIGS modules.
Flexible, lightweight Cu(In,Ga)Se2 (CIGS) solar cells grown on polymer substrates are a promising technology with fast growing market prospects. However, power conversion efficiencies of solar cells grown at low temperatures (≈450 °C) remain below the efficiencies of cells grown at high temperature on glass substrates. This contribution discusses the impact on cell efficiency of process improvements of low‐temperature CIGS deposition on flexible polyimide and glass substrates. Different strategies for incorporation of alkali elements into CIGS are evaluated based on a large number of depositions. Postdeposition treatment with heavy alkali (here RbF) enables a thickness reduction of the CdS buffer layer and increases the open‐circuit voltage. Na supply during 3rd stage CIGS deposition positively impacts the cell performance. Coevaporation of heavy alkali (e.g., RbF) during capping layer deposition mitigates the adverse shunting associated with high Cu contents, yielding highest efficiencies with near‐stoichiometric absorber compositions. Furthermore, optimization of the deposition sequence results in absorbers with a 1 µm wide notch region with nearly constant bandgap minimum. The improved processes result in a record cell efficiency of 20.8% for CIGS on flexible substrate.
We achieved automated optical control over coherent lattice responses that were both time- and position-dependent across macroscopic length scales. In our experiments, spatiotemporal femtosecond pulse shaping was used to generate excitation light fields that were directed toward distinct regions of crystalline samples, producing terahertz-frequency lattice vibrational waves that emanated outward from their multiple origins at lightlike speeds. Interferences among the waves resulted in fully specified far-field responses, including tilted, focusing, or amplified wavefronts. Generation and coherent amplification of terahertz traveling waves and terahertz phased-array generation also were demonstrated.
We study the largely unexplored transition between coherent and noise-seeded incoherent continuum generation in all-normal dispersion (ANDi) fibers and show that highly coherent supercontinua with spectral bandwidths of one octave can be generated with long pump pulses of up to 1.5 ps duration, corresponding to soliton orders of up to N = 600. In terms of N, this corresponds to an approximately 50 times increase of the coherent regime compared to anomalous dispersion pumping. In the transition region between coherent and incoherent spectral broadening we observe the manifestation of nonlinear phenomena that we term incoherent cloud formation and incoherent optical wave breaking, which lead to a gradual or instantaneous coherence collapse of SC spectral components, respectively. The role played by stimulated Raman scattering and parametric four-wave mixing during SC generation in ANDi fibers is shown to be more extensive than previously recognized: their nonlinear coupling contributes to the suppression of incoherent dynamics at short pump pulse durations, while it is responsible for non-phasematched parametric amplification of noise observed in the long pulse regime. We further discuss the dependence of SC coherence on fiber design, and present basic experimental verifications for our findings using single-shot detection of SC spectra generated by picosecond pulses. This work outlines both the further potential as well as the limitations of broadband coherent light source development for applications such as metrology, nonlinear imaging, and ultrafast photonics, amongst others.
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