The most populated conformer of tetrahydrofuran (C(4)H(8)O) has been diagnosed as the Cs conformer in the present study, jointly using experimental electron momentum spectroscopy (EMS) and quantum mechanics. Our B3LYP/6-311++G** model indicates that the C1 conformation, which is one of the three possible conformations of tetrahydrofuran produced by pseudorotation in the gas phase, is a transition state due to its imaginary frequencies, in agreement with the prediction from a recent ab initio MP2/aug-cc-pVTZ study (J. Chem. Phys. 2005, 122, 204303). The study has identified the fingerprint of the highest occupied molecular orbital (HOMO) of the C(s) (12a') conformer as the most populated conformer. The identification of the C(s) structure, therefore, leads to the orbital-based assignment of the ionization binding energy spectra of tetrahydrofuran for the first time, on the basis of the outer valence Green function OVGF/6-31G* model and the density functional theory (DFT) SAOP/ET-PVQZ model. The present study explores an innovative approach to study molecular stabilities. It also indicates that energetic properties are not always the most appropriate means to study conformer-rich biological systems.

Abstract-More-electric aircraft (MEA) has become a dominant trend for modern aircraft. On-board MEA, many functions, which are conventionally driven by pneumatic and hydraulic power, are replaced with electrical subsystems. Starting aircraft engines with an electrical motor instead of using pneumatic power from the auxiliary power unit (APU) is one of the major characteristics of future aircraft. This paper presents the development of a novel electric starter-generator system for aircraft applications. The paper describes the main achievements of the project within the key areas including electric machines, power electronic converters, thermal management and overall system control design. The developed prototype has been tested successfully and the test results are presented in this paper.

This paper proposes a capacitor voltage regulation method for the dual converter with a floating bridge for aerospace applications. This topology has previously been reported, but with a constrained voltage utilisation factor due to the need for capacitor voltage regulations. In this paper, the effect of switching states on the voltage variation of capacitor is quantitatively modelled and an enhanced space vector modulation scheme with current feedback is proposed to achieve an active control of the floating capacitor voltages. This proposed method also allows further exploitation and utilisation of converter voltage. The relationship between the allowed modulation index of dual converter and load power factor is obtained and expressed using a fitted polynomial equation. The advantages of the proposed method include boosted voltage utilisation and superior performance in term of capacitor voltage balance. These advantages have been proven through simulation and experimental results on RL loads as well as with an open-end winding induction motor. The proposed modulation scheme can boost the converter voltage utilisation by at least 10% while achieving full four-level operation. More importantly, the higher available voltage allows extending the constant torque region of the motor, the further beginning of field weakening operation could be postponed.

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With the rapid development of power electronics technology, microgrid (MG) concept has been widely accepted in the field of electrical engineering. Due to the advantages of direct current (DC) distribution systems such as reduced losses and easy integration with energy storage resources, DC MGs have drawn increasing attentions nowadays. With the increase of distributed generation, a DC MG consisting of multiple sources is a hot research topic. The challenge in such a multi-source DC MG is to provide voltage support and good power sharing performance. As the control strategy plays an important role in ensuring MG's power quality and efficiency, a comprehensive review of the state-of-art control approaches in DC MGs is necessary. This paper provides an overview of the primary and secondary control methods under the hierarchical control architecture for DC MGs. Specifically, inner loop and droop control approaches in primary control are reviewed. Centralized, distributed, and decentralized approach based secondary control is discussed in details. Key findings and future trends are also presented at last.

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Abstract-The paper presents control analysis and design for a Permanent Magnet Machine (PMM) operated in Flux-Weakening (FW) mode for an aircraft electric starter-generator application. Previous literature has focused on FW control of PMMs in motoring (starting) mode, however the system stability and control in generating mode has been inadequately studied. The paper reports detailed, rigorous control analysis and design for a PMM based aircraft electric starter-generator operated in flux-weakening mode. It is shown that an unstable area of operation exists. A novel control scheme which eliminates this instability is proposed. The key analytical findings of the paper are verified by experimental investigation. The paper therefore concludes that the presented technique is able to ensure system stability under all modes of operation. Furthermore, it is noted that the findings of this work are also valuable for any two-quadrant PMM drive with frequent change between starting and generating regimes under current-limiting operation.