This paper proposes a capacitor voltage regulation method for the dual converter with a floating bridge for aerospace applications. This topology has previously been reported, but with a constrained voltage utilisation factor due to the need for capacitor voltage regulations. In this paper, the effect of switching states on the voltage variation of capacitor is quantitatively modelled and an enhanced space vector modulation scheme with current feedback is proposed to achieve an active control of the floating capacitor voltages. This proposed method also allows further exploitation and utilisation of converter voltage. The relationship between the allowed modulation index of dual converter and load power factor is obtained and expressed using a fitted polynomial equation. The advantages of the proposed method include boosted voltage utilisation and superior performance in term of capacitor voltage balance. These advantages have been proven through simulation and experimental results on RL loads as well as with an open-end winding induction motor. The proposed modulation scheme can boost the converter voltage utilisation by at least 10% while achieving full four-level operation. More importantly, the higher available voltage allows extending the constant torque region of the motor, the further beginning of field weakening operation could be postponed.

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A critical factor for electronics based on inorganic layered crystals stems from the electrical contact mode between the semiconducting crystals and the metal counterparts in the electric circuit. Here, a materials tailoring strategy via nanocomposite decoration is carried out to reach metallic contact between MoS matrix and transition metal nanoparticles. Nickel nanoparticles (NiNPs) are successfully joined to the sides of a layered MoS crystal through gold nanobuffers, forming semiconducting and magnetic NiNPs@MoS complexes. The intrinsic semiconducting property of MoS remains unchanged, and it can be lowered to only few layers. Chemical bonding of the Ni to the MoS host is verified by synchrotron radiation based photoemission electron microscopy, and further proved by first-principles calculations. Following the system's band alignment, new electron migration channels between metal and the semiconducting side contribute to the metallic contact mechanism, while semiconductor-metal heterojunctions enhance the photocatalytic ability.

In the efforts at controlling automobile emissions, it is important to know in what extent air pollutants from on-road vehicles could be truly reduced. In 2014 we conducted tests in a heavily trafficked tunnel in south China to characterize emissions of volatile organic compounds (VOC) from on-road vehicle fleet and compared our results with those obtained in the same tunnel in 2004. Alkanes, aromatics, and alkenes had average emission factors (EFs) of 338, 63, and 42 mg km in 2014 against that of 194, 129, and 160 mg km in 2004, respectively. In 2014, LPG-related propane, n-butane and i-butane were the top three non-methane hydrocarbons (NMHCs) with EFs of 184 ± 21, 53 ± 6 and 31 ± 3 mg km; the gasoline evaporation marker i-pentane had an average EF of 17 ± 3 mg km; ethylene and propene were the top two alkenes with average EFs of 16 ± 1 and 9.7 ± 0.9 mg km, respectively; isoprene had no direct emission from vehicles; toluene showed the highest EF of 11 ± 2 mg km among the aromatics; and acetylene had an average EF of 7 ± 1 mg km. While EFs of total NMHCs decreased only 9% from 493 ± 120 mg km in 2004 to 449 ± 40 mg km in 2014, their total ozone formation potential (OFP) decreased by 57% from 2.50 × 10 mg km in 2004 to 1.10 × 10 mg km in 2014, and their total secondary organic aerosol formation potential (SOAFP) decreased by 50% from 50 mg km in 2004 to 25 mg km in 2014. The large drop in ozone and SOA formation potentials could be explained by reduced emissions of reactive alkenes and aromatics, due largely to fuel transition from gasoline/diesel to LPG for taxis/buses and upgraded vehicle emission standards.

[1] Forty-five unconnected upward leaders (UULs) occurred in 19 downward negative flashes are analyzed. Each observed UUL is initiated by a downward stepped leader before a new strike point is struck. For each UUL, several parameters are determined when possible mainly by using high-speed images: inception height, inception time prior to return stroke (RS), horizontal distance from the flash's strike point, two-dimensional (2D) distance between the nearest downward leader branch tip and the UUL's inception point at its inception time, 2D length, and 2D average propagation velocity.

Abstract. Particulate amines play an important role for the particle acidity and hygroscopicity and also contribute to secondary organic aerosol mass. We investigated the sources and mixing states of particulate amines using a single-particle aerosol mass spectrometer (SPAMS) during summer and winter 2014 at a rural site in the Pearl River Delta, China. Amine-containing particles accounted for 11.1 and 9.4 % of the total detected individual particles in summer and winter, respectively. Although the increase in amine-containing particle counts mostly occurred at night, no obvious correlations between amine-containing particles and ambient relative humidity (RH) were found during the sampling period. Among the three markers we considered, the most abundant amine marker was 74(C2H5)2NH2+, which was detected in 90 and 86 % of amine-containing particles in summer and winter, followed by amine marker ions of 59(CH3)3N+, and 86(C2H5)2NCH2+ which were detected in less than 10 % of amine-containing particles during sampling period. The amine-containing particles were characterized by high fractions of carbonaceous marker ions, carbon–nitrogen fragments, sulfate, and nitrate in both summer and winter. More than 90 % of amine-containing particles were found to be internally mixed with sulfate throughout the sampling period, while the percentage of amine particles containing nitrate increased from 43 % in summer to 69 % in winter. Robust correlations between the peak intensities of amines, sulfate, and nitrate were observed, suggesting the possible formation of aminium sulfate and nitrate salts. Interestingly, only 8 % of amine particles contained ammonium in summer, while the percentage increased dramatically to 54 % in winter, indicating a relatively ammonium-poor state in summer and an ammonium-rich state in winter. The total ammonium-containing particles were investigated and showed a much lower abundance in ambient particles in summer (3.6 %) than that in winter (32.6 %), which suggests the ammonium-poor state of amine-containing particles in summer may be related to the lower abundance of ammonia/ammonium in gas and particle phases. In addition, higher abundance of amines in ammonium-containing particles than that of ammonium in amine-containing particles suggests a possible contribution of ammonium–amine exchange reactions to the low abundance of ammonium in amine-containing particles at high ambient RH (72 ± 13 %) in summer. The particle acidity of amine-containing particles is estimated via the relative acidity ratio (Ra), which is defined as the ratio of the sum of the sulfate and nitrate peak areas divided by the ammonium peak area. The Ra was 326 ± 326 in summer and 31 ± 13 in winter, indicating that the amine-containing particles were more acidic in summer than in winter. However, after including amines along with the ammonium in the acidity calculation, the new Ra′ values showed no seasonal change in summer (11 ± 4) and winter (10 ± 2), which suggests that amines could be a buffer for the particle acidity of ammonium-poor particles.

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