The recovery and separation of metals from aqueous solutions is one of the research hotspots in hydrometallurgy, environment protection, analytical chemistry, etc. Much attention has been paid to solvent-impregnated resins (SIRs) since these were firstly proposed for the extraction of metals. SIRs are characterized by high efficiency and selectivity, convenient preparation, and easy operation because they combine the unique advantages of solvent extraction and ion exchange. The preparation and features of SIRs are summarized and their applications in the extraction of various metals from solutions are reviewed. In addition, the equilibrium, thermodynamics, and sorption kinetics of the metals onto SIRs are elucidated in detail.
Capacitive deionization (CDI) is a recently developed electrosorption technology for deionization using porous electrodes. The electrode materials play an important role in the efficiency. This paper highlights the current research status of carbon-based materials as the electrode and the adsorption models in the CDI. It includes the types and performances of carbon-based materials and the main influencing factors of the desalination characteristics. Also, operating parameters such as charging voltage, flow rate, concentration of feed solution, treating time and temperature are summarized.
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