2013
DOI: 10.1142/s0218625x13300050
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Desalination by Capacitive Deionization With Carbon-Based Materials as Electrode: A Review

Abstract: Capacitive deionization (CDI) is a recently developed electrosorption technology for deionization using porous electrodes. The electrode materials play an important role in the efficiency. This paper highlights the current research status of carbon-based materials as the electrode and the adsorption models in the CDI. It includes the types and performances of carbon-based materials and the main influencing factors of the desalination characteristics. Also, operating parameters such as charging voltage, flow ra… Show more

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Cited by 46 publications
(24 citation statements)
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“…As mentioned above, increasing the surface area of the ECNFs via different methods is a commonly followed strategy to improve their salt removal capacity from water. However, as pointed out by Huang et al [212], the use of extremely high-surface area carbons may be unprofitable since micropores, which contribute to enhancing the material specific surface area, are hardly accessible for the ions and, hence, not active in CDI process. On the other hand, water wettability is known to be very beneficial to the diffusion and adsorption of ions in the solution to the fiber surface and results in improved surface utilization [212].…”
Section: Capacitive Deionization Of Watermentioning
confidence: 99%
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“…As mentioned above, increasing the surface area of the ECNFs via different methods is a commonly followed strategy to improve their salt removal capacity from water. However, as pointed out by Huang et al [212], the use of extremely high-surface area carbons may be unprofitable since micropores, which contribute to enhancing the material specific surface area, are hardly accessible for the ions and, hence, not active in CDI process. On the other hand, water wettability is known to be very beneficial to the diffusion and adsorption of ions in the solution to the fiber surface and results in improved surface utilization [212].…”
Section: Capacitive Deionization Of Watermentioning
confidence: 99%
“…However, as pointed out by Huang et al [212], the use of extremely high-surface area carbons may be unprofitable since micropores, which contribute to enhancing the material specific surface area, are hardly accessible for the ions and, hence, not active in CDI process. On the other hand, water wettability is known to be very beneficial to the diffusion and adsorption of ions in the solution to the fiber surface and results in improved surface utilization [212]. It is widely recognized that a high N-doping level of the active material is beneficial for the wettability of the electrode surface and pseudo-capacitance, as well [6,195].…”
Section: Capacitive Deionization Of Watermentioning
confidence: 99%
“…The stored ions are released from the electrodes resulting in a brine stream with significantly higher concentration than the feed. The whole process is known as electrosorption .…”
Section: Removal Of Inorganic Compoundsmentioning
confidence: 99%
“…Over the last few decades, CDI has become remarkably advanced with various types of electrodes including capacitive electrodes with carbonaceous materials (i.e., activated carbon, carbon aerogel, carbon nanotubes, and graphene) [11][12][13][14][15] and faradaic electrodes with battery and battery-like materials (i.e., sodium manganese oxide, molybdenum disulfide, Mxene, silver/silver chloride, and Prussian blue analogs) [16][17][18][19][20]. These electrode materials have led to novel systematic developments.…”
Section: Introductionmentioning
confidence: 99%